#P HF/6-31G(d) freq

HF/6-31G(d) freq CH3OH (Cs)

0 1
H1
C2  1  r2
O3  2  r3  1  a3
H4  3  r4  2  a4  1  180.0
H5  2  r5  3  a5  1  d5
H6  2  r5  3  a5  1  -d5

r2=1.08105957
r3=1.39956997
r4=0.94629421
r5=1.08744287
a3=107.170012
a4=109.447010
a5=112.035787
d5=118.773010