Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Alkyl, Alkenyl and Aryl Boron Compounds

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
Found 38 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
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(5-methyl-furan-2-yl) pinacol boronate		MeCNN  Parameter: 2.90
sN Parameter: 0.98		***Chem. Sci. 2012, 3, 878-882
DOI: 10.1039/c2sc00883a
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(5-methyl-furan-2-yl) MDA boronate		MeCNN  Parameter: 6.38
sN Parameter: 0.86		***Chem. Sci. 2012, 3, 878-882
DOI: 10.1039/c2sc00883a
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(5-methyl-furan-2-yl) MIDA boronate		MeCNN  Parameter: 1.84
sN Parameter: 1.26		**Chem. Sci. 2012, 3, 878-882
DOI: 10.1039/c2sc00883a
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(5-methyl-furan-2-yl) trifluoroborate		MeCNN  Parameter: 7.66
sN Parameter: 1.04		***Chem. Sci. 2012, 3, 878-882
DOI: 10.1039/c2sc00883a
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tetrakis(5-methyl-furan-2-yl)borate		MeCNN  Parameter: 9.09
sN Parameter: 1.12		***Chem. Sci. 2012, 3, 878-882
DOI: 10.1039/c2sc00883a
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(5-methyl-furan-2-yl)(1,1,1-tris(methoxy)ethane)borate		MeCNN  Parameter: 12.55
sN Parameter: 0.92		***Chem. Sci. 2012, 3, 878-882
DOI: 10.1039/c2sc00883a
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potassium trifluoro(1-methyl-1H-indol-2-yl)borate		MeCNN  Parameter: 9.55
sN Parameter: 1.16		***J. Am. Chem. Soc. 2013, 135, 6317-6324
DOI: 10.1021/ja4017655
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potassium trifluoro(1-methyl-1H-indol-5-yl)borate		MeCNN  Parameter: 8.77
sN Parameter: 1.09		***J. Am. Chem. Soc. 2013, 135, 6317-6324
DOI: 10.1021/ja4017655
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potassium (1-(tert-butoxycarbonyl)-1H-indol-2-yl)trifluoroborate		MeCNN  Parameter: 6.46
sN Parameter: 0.96		***J. Am. Chem. Soc. 2013, 135, 6317-6324
DOI: 10.1021/ja4017655
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potassium (1-(tert-butoxycarbonyl)-5-methoxy-1H-indol-2-yl)trifluoroborate		MeCNN  Parameter: 7.10
sN Parameter: 1.18		***J. Am. Chem. Soc. 2013, 135, 6317-6324
DOI: 10.1021/ja4017655
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potassium (1-(tert-butoxycarbonyl)-1H-indol-3-yl)trifluoroborate		MeCNN  Parameter: 4.06
sN Parameter: 0.79		**J. Am. Chem. Soc. 2013, 135, 6317-6324
DOI: 10.1021/ja4017655
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potassium trifluoro(furan-2-yl)borate		MeCNN  Parameter: 5.99
sN Parameter: 0.79		**J. Am. Chem. Soc. 2013, 135, 6317-6324
DOI: 10.1021/ja4017655
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potassium trifluoro(furan-3-yl)borate		MeCNN  Parameter: 6.83
sN Parameter: 0.93		***J. Am. Chem. Soc. 2013, 135, 6317-6324
DOI: 10.1021/ja4017655
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potassium trifluoro(3-methoxy-thiophen-2-yl)borate		MeCNN  Parameter: 7.32
sN Parameter: 0.90		***J. Am. Chem. Soc. 2013, 135, 6317-6324
DOI: 10.1021/ja4017655
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lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)pinacolborate		MeCNN  Parameter: 5.53
sN Parameter: 1.00		*Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)pinacolborate		MeCNN  Parameter: 6.24
sN Parameter: 1.00		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(4-chlorophenyl)pinacolborate		MeCNN  Parameter: 6.77
sN Parameter: 0.88		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(phenyl)pinacolborate		MeCNN  Parameter: 7.24
sN Parameter: 0.83		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(4-methylphenyl)pinacolborate		MeCNN  Parameter: 6.98
sN Parameter: 0.93		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(4-methoxyphenyl)pinacolborate		MeCNN  Parameter: 7.51
sN Parameter: 0.87		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(4-(dimethylamino)phenyl)pinacolborate		MeCNN  Parameter: 8.02
sN Parameter: 0.89		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium bis(5-methylthiophen-2-yl)pinacolborate		MeCNN  Parameter: 7.67
sN Parameter: 0.87		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylfuran-2-yl)(4-(trifluoromethyl)phenyl)pinacolborate		MeCNN  Parameter: 8.13
sN Parameter: 0.85		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)glycolborate		MeCNN  Parameter: 11.23
sN Parameter: 0.77		***Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)neopentylglycolborate		MeCNN  Parameter: 10.13
sN Parameter: 0.91		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)neopentylglycolborate		MeCNN  Parameter: 11.85
sN Parameter: 0.72		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)catecholglycolborate		MeCNN  Parameter: 6.50
sN Parameter: 0.77		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
DOI: 10.1002/anie.201410562
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lithium 2-benzyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 8.92
sN Parameter: 0.70		**Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 4,4,5,5-tetramethyl-2-phenyl-2-(1-phenylethyl)-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 10.97
sN Parameter: 0.63		**Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 2-benzyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 7.15
sN Parameter: 0.77		***Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 4,4,5,5-tetramethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 8.56
sN Parameter: 0.76		***Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-2-(1-phenylethyl)-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 7.46
sN Parameter: 0.76		**Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 2-benzyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 6.30
sN Parameter: 0.78		**Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 2-isopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 6.63
sN Parameter: 0.75		*Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 2-cyclopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 7.72
sN Parameter: 0.75		*Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 2-ethyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 7.68
sN Parameter: 0.78		***Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 5,5-dimethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborinan-2-uide (in MeCN)		MeCNN  Parameter: 11.29
sN Parameter: 0.76		***Org. Lett. 2015, 17, 2614-2617
DOI: 10.1021/acs.orglett.5b00918
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lithium 4,4,5,5-tetramethyl-2-phenyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolan-2-uide (in MeCN)		MeCNN  Parameter: 11.00
sN Parameter: 0.57		***J. Am. Chem. Soc. 2022, 144, 16118-16130
DOI: 10.1021/jacs.2c06493
 
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