NHOs (conventional and mesoionic)

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles

Found 19 Molecules.

Molecule	Solvent	Reactivity Parameters	Reference (sort by title or year)
1,3-dimethyl-2-methyleneimidazolidine (in THF)	THF	N Parameter: 18.11 s_N Parameter: 0.68	J. Org. Chem. 2021, 86, 2974-2985 DOI: 10.1021/acs.joc.0c02838
1,3-dimethyl-2-methylenehexahydropyrimidine (in THF)	THF	N Parameter: 18.68 s_N Parameter: 0.63	J. Org. Chem. 2021, 86, 2974-2985 DOI: 10.1021/acs.joc.0c02838
1,3-dimesityl-2-methylene-2,3-dihydro-1H-imidazole (in THF)	THF	N Parameter: 17.80 s_N Parameter: 0.79	J. Org. Chem. 2021, 86, 2974-2985 DOI: 10.1021/acs.joc.0c02838
1,3-dimethyl-2-methylene-2,3-dihydro-1H-benzo[d]imidazole	THF	N Parameter: 19.84 s_N Parameter: 0.58	J. Org. Chem. 2021, 86, 2974-2985 DOI: 10.1021/acs.joc.0c02838
1,3-Bis(2,6-diisopropylphenyl)-5-methylene-4-(2,4,6-triisopropylphenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-4-ide (in THF)	THF	N Parameter: 21.36 s_N Parameter: 0.42	Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790
1,3-Bis(2,6-diisopropylphenyl)-4-methylene-5-(4-(trifluoromethyl)phenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Parameter: 22.30 s_N Parameter: 0.49	Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790
1,3-Bis(2,6-diisopropylphenyl)-5-(4-methoxyphenyl)-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Parameter: 23.55 s_N Parameter: 0.56	Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790
1,3-Bis(2,6-diisopropylphenyl)-5-methylene-4-(2,4,6-triisopropylphenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-4-ide (in THF)	THF	N Parameter: 20.78 s_N Parameter: 0.61	Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790
1,3-Diisopropyl-4-methylene-5-phenyl-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Parameter: 30.25 s_N Parameter: 0.54	Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790
5-(tert-Butyl)-1,3-diisopropyl-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Parameter: 31.92 s_N Parameter: 0.52	Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790
1,3-bis(2,6-diisopropylphenyl)-4-methylene-5-phenyl-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Parameter: 22.80 s_N Parameter: 0.60	Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790
1,3-bis(2,6-diisopropylphenyl)-5-methyl-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Parameter: 24.86 s_N Parameter: 0.52	Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790
1-mesityl-3-methyl-5-methylene-2,4,6-triphenyl-2,5-dihydropyridin-1-ium-2-ide (in THF)	THF	N Parameter: 26.16 s_N Parameter: 0.52	Angew. Chem. Int. Ed. 2024, , e202318283 DOI: 10.1002/anie.202318283
1,3-dimethyl-2-methylene-1,2-dihydropyridine (in MeCN)	MeCN	N Parameter: 19.69 s_N Parameter: 0.61	Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373
1,3,5-trimethyl-2-methylene-1,2-dihydropyridine (in DMSO)	DMSO	N Parameter: 21.16 s_N Parameter: 0.59	Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373
1,3-dimethyl-2-methylene-1,2-dihydropyridine (in DMSO)	DMSO	N Parameter: 19.91 s_N Parameter: 0.62	Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373
1,6-dimethyl-2-methylene-1,2-dihydropyridine (in DMSO)	DMSO	N Parameter: 20.76 s_N Parameter: 0.60	Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373
1-methyl-2-methylene-3-phenyl-1,2-dihydropyridine (in DMSO)	DMSO	N Parameter: 19.41 s_N Parameter: 0.61	Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373
1-(4-(tert-butyl)phenyl)-2-methylene-4,6-diphenyl-1,2-dihydropyridine (in DMSO)	DMSO	N Parameter: 19.36 s_N Parameter: 0.68	Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373