Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Carbanions

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
Found 155 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
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enolate of 3-isochromanone (in DMSO)
DMSON  Parameter: 25.39
sN Parameter: 0.54
***J. Org. Chem. 2024, 89, 6915-6928
DOI: 10.1021/acs.joc.4c00277
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enolate of 2-coumaranone (in DMSO)
DMSON  Parameter: 19.60
sN Parameter: 0.75
***J. Org. Chem. 2024, 89, 6915-6928
DOI: 10.1021/acs.joc.4c00277
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anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in MeCN)
MeCNN  Parameter: 16.15
sN Parameter: 0.99
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
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anion of 4-cyanobenzyl trifluoromethyl sulfone (in MeCN)
MeCNN  Parameter: 15.62
sN Parameter: 0.99
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
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anion of 4-nitrobenzyl-CN (in MeCN)
MeCNN  Parameter: 20.10
sN Parameter: 0.71
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
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anion of (4-NO2-C6H4)CH2SO2Ph (in MeCN)
MeCNN  Parameter: 19.90
sN Parameter: 0.66
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
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1-((diphenylmethylene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)
DMSON  Parameter: 26.95
sN Parameter: 0.52
***Tetrahedron 2019, 75, 459-463
DOI: 10.1016/j.tet.2018.11.075
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2-(tert-butoxy)-1-((diphenylmethylene)amino)-2-oxoethan-1-ide (in DMSO)
DMSON  Parameter: 27.77
sN Parameter: 0.47
***Tetrahedron 2019, 75, 459-463
DOI: 10.1016/j.tet.2018.11.075
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1-(benzylideneamino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)
DMSON  Parameter: 29.10
sN Parameter: 0.50
*Tetrahedron 2019, 75, 459-463
DOI: 10.1016/j.tet.2018.11.075
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1-((4-chlorobenzylidene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)
DMSON  Parameter: 29.02
sN Parameter: 0.49
**Tetrahedron 2019, 75, 459-463
DOI: 10.1016/j.tet.2018.11.075
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2-(benzylideneamino)-1-ethoxy-1-oxopropan-2-ide (in DMSO)
DMSON  Parameter: 30.82
sN Parameter: 0.41
**Tetrahedron 2019, 75, 459-463
DOI: 10.1016/j.tet.2018.11.075
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cyano((diphenylmethylene)amino)methanide
DMSON  Parameter: 29.50
sN Parameter: 0.50
*Tetrahedron 2019, 75, 459-463
DOI: 10.1016/j.tet.2018.11.075
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1-ethoxy-3-(4-nitrophenyl)-1,3-dioxopropan-2-ide (in DMSO)
DMSON  Parameter: 16.26
sN Parameter: 0.83
***J. Am. Chem. Soc. 2018, 140, 11474-11486
DOI: 10.1021/jacs.8b07147
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chloro(phenylsulfonyl)methanide (in DMSO)
DMSON  Parameter: 28.27
sN Parameter: 0.42
***J. Org. Chem. 2017, 82, 2011-2017
DOI: 10.1021/acs.joc.6b02844
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bromo(phenylsulfonyl)methanide (in DMSO)
DMSON  Parameter: 23.90
sN Parameter: 0.62
***J. Org. Chem. 2017, 82, 2011-2017
DOI: 10.1021/acs.joc.6b02844
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chloro((4-cyanophenyl)sulfonyl)methanide (in DMSO)
DMSON  Parameter: 25.59
sN Parameter: 0.51
***J. Org. Chem. 2017, 82, 2011-2017
DOI: 10.1021/acs.joc.6b02844
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chloro((4-nitrophenyl)sulfonyl)methanide (in DMSO)
DMSON  Parameter: 24.88
sN Parameter: 0.49
***J. Org. Chem. 2017, 82, 2011-2017
DOI: 10.1021/acs.joc.6b02844
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chloro((4-chlorophenyl)sulfonyl)methanide (in DMSO)
DMSON  Parameter: 26.90
sN Parameter: 0.45
***J. Org. Chem. 2017, 82, 2011-2017
DOI: 10.1021/acs.joc.6b02844
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anion of ethyl 2-cyano-2-phenylacetate (in DMSO)
DMSON  Parameter: 15.85
sN Parameter: 1.04
***Eur. J. Org. Chem. 2017, , 1196-1202
DOI: 10.1002/ejoc.201601513
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anion of 2-phenylmalononitrile (in DMSO)
DMSON  Parameter: 15.58
sN Parameter: 1.00
***Eur. J. Org. Chem. 2017, , 1196-1202
DOI: 10.1002/ejoc.201601513
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anion of 2-phenyl-2-(phenylsulfonyl)acetonitrile (in DMSO)
DMSON  Parameter: 15.97
sN Parameter: 0.72
***Eur. J. Org. Chem. 2017, , 1196-1202
DOI: 10.1002/ejoc.201601513
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anion of (phenylmethylenedisulfonyl)dibenzene (in DMSO)
DMSON  Parameter: 15.07
sN Parameter: 0.79
***Eur. J. Org. Chem. 2017, , 1196-1202
DOI: 10.1002/ejoc.201601513
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anion of 1,2,3-triphenylpropane-1,3-dione (in DMSO)
DMSON  Parameter: 14.99
sN Parameter: 0.83
***Eur. J. Org. Chem. 2017, , 1196-1202
DOI: 10.1002/ejoc.201601513
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barbiturate anion (in DMSO)
DMSON  Parameter: 15.59
sN Parameter: 0.80
***J. Org. Chem. 2017, 82, 8476-8488
DOI: 10.1021/acs.joc.7b01223
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1,3-dimethylbarbiturate anion (in DMSO)
DMSON  Parameter: 17.46
sN Parameter: 0.72
***J. Org. Chem. 2017, 82, 8476-8488
DOI: 10.1021/acs.joc.7b01223
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2-thiobarbiturate anion (in DMSO)
DMSON  Parameter: 14.24
sN Parameter: 0.82
***J. Org. Chem. 2017, 82, 8476-8488
DOI: 10.1021/acs.joc.7b01223
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1,3-diethyl-thiobarbiturate anion (in DMSO)
DMSON  Parameter: 14.90
sN Parameter: 0.80
***J. Org. Chem. 2017, 82, 8476-8488
DOI: 10.1021/acs.joc.7b01223
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anion of diethyl 2-(isopropyl)malonate (in DMSO)
DMSON  Parameter: 18.74
sN Parameter: 0.71
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of diethyl 2-butylmalonate (in DMSO)
DMSON  Parameter: 23.00
sN Parameter: 0.55
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of diethyl 2-cyclohexylmalonate (in DMSO)
DMSON  Parameter: 19.23
sN Parameter: 0.67
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of diethyl 2-phenylmalonate (in DMSO)
DMSON  Parameter: 15.93
sN Parameter: 0.99
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of diethyl 2-(4-nitrophenyl)malonate (in DMSO)
DMSON  Parameter: 14.94
sN Parameter: 0.96
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of triethyl methanetricarboxylate (in DMSO)
DMSON  Parameter: 15.33
sN Parameter: 0.72
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of diethyl 2-(acetyl)malonate (in DMSO)
DMSON  Parameter: 13.83
sN Parameter: 0.84
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of diethyl 2-(benzoyl)malonate (in DMSO)
DMSON  Parameter: 13.63
sN Parameter: 0.80
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of 5-phenyl Meldrum's acid (in DMSO)
DMSON  Parameter: 11.54
sN Parameter: 0.95
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of 5-(p-anisyl) Meldrum's acid (in DMSO)
DMSON  Parameter: 12.35
sN Parameter: 0.90
**Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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anion of diethyl 2-(p-anisyl)malonate (in DMSO)
DMSON  Parameter: 16.73
sN Parameter: 0.91
***Eur. J. Org. Chem. 2016, , 1841-1848
DOI: 10.1002/ejoc.201600107
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bis(phenylsulfonyl)methanide (in DMSO)
DMSON  Parameter: 15.68
sN Parameter: 0.74
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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fluorobis(phenylsulfonyl)methanide (in DMSO)
DMSON  Parameter: 17.46
sN Parameter: 0.73
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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methoxybis(phenylsulfonyl)methanide (in DMSO)
DMSON  Parameter: 17.29
sN Parameter: 0.70
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
DMSON  Parameter: 16.06
sN Parameter: 0.69
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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2-fluoro-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
DMSON  Parameter: 19.03
sN Parameter: 0.58
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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2-methoxy-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
DMSON  Parameter: 17.36
sN Parameter: 0.71
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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2-ethoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
DMSON  Parameter: 18.81
sN Parameter: 0.59
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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2-ethoxy-1-fluoro-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
DMSON  Parameter: 20.51
sN Parameter: 0.64
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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2-ethoxy-1-methoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
DMSON  Parameter: 19.15
sN Parameter: 0.59
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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1,3-diethoxy-2-fluoro-1,3-dioxopropan-2-ide (in DMSO)
DMSON  Parameter: 20.63
sN Parameter: 0.76
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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2-chloro-1,3-diethoxy-1,3-dioxopropan-2-ide (in DMSO)
DMSON  Parameter: 18.19
sN Parameter: 0.74
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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1,2,3-trimethoxy-1,3-dioxopropan-2-ide (in DMSO)
DMSON  Parameter: 20.08
sN Parameter: 0.74
***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
DOI: 10.1002/anie.201605616
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anion of 1,2-diphenylethanone (in DMSO)
DMSON  Parameter: 23.15
sN Parameter: 0.60
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of N,N-diethyl-3-oxo-3-phenylpropanoate (in DMSO)
DMSON  Parameter: 19.28
sN Parameter: 0.65
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of ethyl 3-oxo-3-phenylpropanoate (in DMSO)
DMSON  Parameter: 17.52
sN Parameter: 0.74
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of 3-oxo-3-phenylpropanenitrile (in DMSO)
DMSON  Parameter: 16.55
sN Parameter: 0.78
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of 1-phenylbutane-1,3-dione (in DMSO)
DMSON  Parameter: 16.03
sN Parameter: 0.86
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of 1,3-diphenylpropane-1,3-dione (in DMSO)
DMSON  Parameter: 17.46
sN Parameter: 0.65
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of 1-phenyl-2-(phenylsulfonyl)ethanone (in DMSO)
DMSON  Parameter: 17.19
sN Parameter: 0.56
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of 2-nitro-1-phenylethan-1-one (in DMSO)
DMSON  Parameter: 13.91
sN Parameter: 0.76
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of 1-phenylpropan-2-one (in DMSO)
DMSON  Parameter: 24.99
sN Parameter: 0.60
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of (benzylsulfonyl)benzene (in DMSO)
DMSON  Parameter: 25.77
sN Parameter: 0.56
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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anion of ethyl 2-nitroacetate (in DMSO)
DMSON  Parameter: 15.24
sN Parameter: 0.74
***Chem. Eur. J. 2015, 21, 875-884
DOI: 10.1002/chem.201404500
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potassium indenide (in DMSO)
DMSON  Parameter: 24.16
sN Parameter: 0.68
***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
DOI: 10.1002/anie.201501385
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sodium indenide (in DMSO)
DMSON  Parameter: 23.74
sN Parameter: 0.71
***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
DOI: 10.1002/anie.201501385
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lithium indenide (in DMSO)
DMSON  Parameter: 23.66
sN Parameter: 0.70
***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
DOI: 10.1002/anie.201501385
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1-ethoxy-2-methyl-1,3-dioxobutan-2-ide (in DMSO)
DMSON  Parameter: 19.58
sN Parameter: 0.73
***Eur. J. Org. Chem. 2015, , 7594-7601
DOI: 10.1002/ejoc.201501107
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1-(ethoxycarbonyl)-2-oxocyclopentan-1-ide (in DMSO)
DMSON  Parameter: 18.63
sN Parameter: 0.82
***Eur. J. Org. Chem. 2015, , 7594-7601
DOI: 10.1002/ejoc.201501107
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1-(ethoxycarbonyl)-2-oxocyclohexan-1-ide (in DMSO)
DMSON  Parameter: 18.32
sN Parameter: 0.84
***Eur. J. Org. Chem. 2015, , 7594-7601
DOI: 10.1002/ejoc.201501107
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1-(ethoxycarbonyl)-2-oxocycloheptan-1-ide
DMSON  Parameter: 19.53
sN Parameter: 0.83
***Eur. J. Org. Chem. 2015, , 7594-7601
DOI: 10.1002/ejoc.201501107
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1-(ethoxycarbonyl)-2-oxocyclooctan-1-ide (in DMSO)
DMSON  Parameter: 20.02
sN Parameter: 0.76
***Eur. J. Org. Chem. 2015, , 7594-7601
DOI: 10.1002/ejoc.201501107
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1-(ethoxycarbonyl)-2-oxocyclododecan-1-ide (in DMSO)
DMSON  Parameter: 20.60
sN Parameter: 0.63
***Eur. J. Org. Chem. 2015, , 7594-7601
DOI: 10.1002/ejoc.201501107
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3-methyl-2,4-dioxotetrahydro-2H-pyran-3-ide (in DMSO)
DMSON  Parameter: 14.46
sN Parameter: 0.91
***Eur. J. Org. Chem. 2015, , 7594-7601
DOI: 10.1002/ejoc.201501107
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3-acetyl-2-oxotetrahydro-2H-pyran-3-ide (in DMSO)
DMSON  Parameter: 17.00
sN Parameter: 0.74
***Eur. J. Org. Chem. 2015, , 7594-7601
DOI: 10.1002/ejoc.201501107
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5-(4-(dimethylamino)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
DMSON  Parameter: 14.48
sN Parameter: 0.86
***Chem. Eur. J. 2014, 20, 11069-11077
DOI: 10.1002/chem.201403161
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5-(4-(methoxy)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
DMSON  Parameter: 15.13
sN Parameter: 0.75
***Chem. Eur. J. 2014, 20, 11069-11077
DOI: 10.1002/chem.201403161
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5-benzyl-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
DMSON  Parameter: 15.02
sN Parameter: 0.75
***Chem. Eur. J. 2014, 20, 11069-11077
DOI: 10.1002/chem.201403161
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5-(4-cyanobenzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
DMSON  Parameter: 13.79
sN Parameter: 0.86
***Chem. Eur. J. 2014, 20, 11069-11077
DOI: 10.1002/chem.201403161
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2,2-dimethyl-5-(4-nitrobenzyl)-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
DMSON  Parameter: 12.02
sN Parameter: 1.17
***Chem. Eur. J. 2014, 20, 11069-11077
DOI: 10.1002/chem.201403161
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2-PhCH(-)CO2Et (in DMSO)
DMSON  Parameter: 27.54
sN Parameter: 0.57
***Eur. J. Org. Chem. 2013, , 4255-4261
DOI: 10.1002/ejoc.201300265
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2-(3-Cl-C6H4)CH(-)CO2Et (in DMSO)
DMSON  Parameter: 27.57
sN Parameter: 0.53
***Eur. J. Org. Chem. 2013, , 4255-4261
DOI: 10.1002/ejoc.201300265
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2-(4-Br-C6H4)CH(-)CO2Et (in DMSO)
DMSON  Parameter: 27.62
sN Parameter: 0.53
***Eur. J. Org. Chem. 2013, , 4255-4261
DOI: 10.1002/ejoc.201300265
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2-(4-CN-C6H4)CH(-)CO2Et (in DMSO)
DMSON  Parameter: 23.64
sN Parameter: 0.65
***Eur. J. Org. Chem. 2013, , 4255-4261
DOI: 10.1002/ejoc.201300265
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2-(4-NO2-C6H4)CH(-)CO2Et (in DMSO)
DMSON  Parameter: 20.00
sN Parameter: 0.71
***Eur. J. Org. Chem. 2013, , 4255-4261
DOI: 10.1002/ejoc.201300265
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2-(pyrid-4-yl)CH(-)CO2Et (in DMSO)
DMSON  Parameter: 23.27
sN Parameter: 0.70
***Eur. J. Org. Chem. 2013, , 4255-4261
DOI: 10.1002/ejoc.201300265
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MeSO2-CH-CO2Et (in DMSO)
DMSON  Parameter: 18.00
sN Parameter: 0.66
***Chem. Eur. J. 2010, 16, 8610-8614
DOI: 10.1002/chem.201001455
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MeSO-CH-CO2Et (in DMSO)
DMSON  Parameter: 20.61
sN Parameter: 0.64
***Chem. Eur. J. 2010, 16, 8610-8614
DOI: 10.1002/chem.201001455
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anion of 4-(trifluoromethyl)benzyl-CN (in DMSO)
DMSON  Parameter: 27.28
sN Parameter: 0.50
***J. Org. Chem. 2009, 74, 75-81
DOI: 10.1021/jo802241x
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anion of 4-cyanobenzyl-CN (in DMSO)
DMSON  Parameter: 25.11
sN Parameter: 0.54
***J. Org. Chem. 2009, 74, 75-81
DOI: 10.1021/jo802241x
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anion of 4-nitrobenzyl-CN (in DMSO)
DMSON  Parameter: 19.67
sN Parameter: 0.68
***J. Org. Chem. 2009, 74, 75-81
DOI: 10.1021/jo802241x
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anion of 2-phenyl-propionitrile (in DMSO)
DMSON  Parameter: 28.95
sN Parameter: 0.58
***J. Org. Chem. 2009, 74, 75-81
DOI: 10.1021/jo802241x
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anion of 2-(4-CN-C6H4)propionitrile (in DMSO)
DMSON  Parameter: 25.35
sN Parameter: 0.56
***J. Org. Chem. 2009, 74, 75-81
DOI: 10.1021/jo802241x
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anion of 2-(4-NO2-C6H4)propionitrile (in DMSO)
DMSON  Parameter: 19.61
sN Parameter: 0.60
***J. Org. Chem. 2009, 74, 75-81
DOI: 10.1021/jo802241x
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(EtO)2P(O)CH(-)CO2Et (in DMSO)
DMSON  Parameter: 19.23
sN Parameter: 0.65
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
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(EtO)2P(O)CH(-)CN (in DMSO)
DMSON  Parameter: 18.57
sN Parameter: 0.66
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
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Ph2P(O)CH(-)CO2Et (in DMSO)
DMSON  Parameter: 19.20
sN Parameter: 0.69
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
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Ph2P(O)CH(-)CN (in DMSO)
DMSON  Parameter: 18.69
sN Parameter: 0.72
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
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bis(4-nitrophenyl)methanide (in DMSO)
DMSON  Parameter: 19.92
sN Parameter: 0.67
***ARKIVOC 2008, (x), 37-53
DOI: 10.3998/ark.5550190.0009.a05
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anion of (4-NO2-C6H4)CH2SO2Ph (in DMSO)
DMSON  Parameter: 18.50
sN Parameter: 0.75
***Org. Biomol. Chem. 2008, 6, 3052-3058
DOI: 10.1039/b805604h
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anion of (4-CN-C6H4)CH2SO2Ph (in DMSO)
DMSON  Parameter: 22.60
sN Parameter: 0.57
***Org. Biomol. Chem. 2008, 6, 3052-3058
DOI: 10.1039/b805604h
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anion of (4-CF3-C6H4)CH2SO2Ph (in DMSO)
DMSON  Parameter: 24.30
sN Parameter: 0.51
***Org. Biomol. Chem. 2008, 6, 3052-3058
DOI: 10.1039/b805604h
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anion of nitroethane (in DMF)
DMFN  Parameter: 22.21
sN Parameter: 0.48
***Chem. Eur. J. 2008, 14, 6108-6118
DOI: 10.1002/chem.200800329
image of molecule

chloro(phenylsulfonyl)methanide (in DMF)
DMFN  Parameter: 26.64
sN Parameter: 0.64
-Chem. Eur. J. 2008, 14, 6108-6118
DOI: 10.1002/chem.200800329
image of molecule

anion of 4-nitrobenzyl trifluoromethyl sulfone (in DMSO)
DMSON  Parameter: 14.49
sN Parameter: 0.86
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of 4-cyanobenzyl trifluoromethyl sulfone (in DMSO)
DMSON  Parameter: 16.28
sN Parameter: 0.75
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in DMSO)
DMSON  Parameter: 17.33
sN Parameter: 0.74
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of benzyl trifluoromethyl sulfone (in DMSO)
DMSON  Parameter: 18.67
sN Parameter: 0.68
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of 4-methylbenzyl trifluoromethyl sulfone (in DMSO)
DMSON  Parameter: 19.35
sN Parameter: 0.67
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of 4-nitrobenzyl trifluoromethyl sulfone (in 91M9AN)
MeOH-MeCN mixN  Parameter: 18.24
sN Parameter: 0.66
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of 4-cyanobenzyl trifluoromethyl sulfone (in 91M9AN)
MeOH-MeCN mixN  Parameter: 19.49
sN Parameter: 0.63
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN)
MeOH-MeCN mixN  Parameter: 20.72
sN Parameter: 0.58
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of nitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 14.02
sN Parameter: 0.61
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of nitroethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 13.41
sN Parameter: 0.67
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of 2-nitropropane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 12.20
sN Parameter: 0.71
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of phenylnitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 12.51
sN Parameter: 0.67
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of p-tolylnitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 13.58
sN Parameter: 0.64
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of (4-nitrophenyl)nitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 14.05
sN Parameter: 0.72
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of (3-nitrophenyl)nitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 14.75
sN Parameter: 0.71
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of (4-cyanophenyl)nitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 13.92
sN Parameter: 0.74
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of ethyl cyanoacetate (in 91M9AN)
MeOH-MeCN mixN  Parameter: 18.59
sN Parameter: 0.65
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of malononitrile (in 91M9AN)
MeOH-MeCN mixN  Parameter: 18.21
sN Parameter: 0.69
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of dimethyl malonate (in 91M9AN)
MeOH-MeCN mixN  Parameter: 18.24
sN Parameter: 0.64
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

cyanide (in MeCN)
MeCNN  Parameter: 16.27
sN Parameter: 0.70
***Angew. Chem. Int. Ed. 2005, 44, 142-145
DOI: 10.1002/anie.200461640
image of molecule

anion of nitroethane (in water)
waterN  Parameter: 11.25
sN Parameter: 0.52
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of nitromethane (in water)
waterN  Parameter: 12.06
sN Parameter: 0.53
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of nitromethane (in DMSO)
DMSON  Parameter: 20.71
sN Parameter: 0.60
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of 2-nitropropane (in DMSO)
DMSON  Parameter: 20.61
sN Parameter: 0.69
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of 2-nitropropane (in water)
waterN  Parameter: 10.69
sN Parameter: 0.56
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of phenylnitromethane (in H2O)
waterN  Parameter: 12.05
sN Parameter: 0.53
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of phenylnitromethane (in DMSO)
DMSON  Parameter: 18.29
sN Parameter: 0.71
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of p-tolylnitromethane (in water)
waterN  Parameter: 13.09
sN Parameter: 0.50
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of p-tolylnitromethane (in DMSO)
DMSON  Parameter: 18.31
sN Parameter: 0.76
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of (4-nitrophenyl)nitromethane (in water)
waterN  Parameter: 13.58
sN Parameter: 0.52
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of (4-nitrophenyl)nitromethane (in DMSO)
DMSON  Parameter: 16.29
sN Parameter: 0.75
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of (3-nitrophenyl)nitromethane (in water)
waterN  Parameter: 14.25
sN Parameter: 0.46
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of (3-nitrophenyl)nitromethane (in DMSO)
DMSON  Parameter: 18.06
sN Parameter: 0.71
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of (4-cyanophenyl)nitromethane (in water)
waterN  Parameter: 13.23
sN Parameter: 0.52
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of (4-cyanophenyl)nitromethane (in DMSO)
DMSON  Parameter: 16.96
sN Parameter: 0.73
***J. Org. Chem. 2004, 69, 7565-7576
DOI: 10.1021/jo048773j
image of molecule

anion of nitroethane (in DMSO)
DMSON  Parameter: 21.54
sN Parameter: 0.62
***J. Org. Chem. 2003, 68, 6880-6886
DOI: 10.1021/jo0344182
image of molecule

anion of Meldrum's acid (in water)
waterN  Parameter: 12.06
sN Parameter: 0.66
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of dimedone (in water)
waterN  Parameter: 11.77
sN Parameter: 0.63
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of acetylacetone (in water)
waterN  Parameter: 13.73
sN Parameter: 0.64
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of ethyl acetylacetate (in water)
waterN  Parameter: 15.99
sN Parameter: 0.62
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of malononitrile (in water)
waterN  Parameter: 19.50
sN Parameter: 0.55
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of ethyl cyanoacetate (in water)
waterN  Parameter: 15.57
sN Parameter: 0.58
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of diethyl malonate (in water)
waterN  Parameter: 16.15
sN Parameter: 0.66
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of diethyl methylmalonate (in DMSO)
DMSON  Parameter: 21.13
sN Parameter: 0.68
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of diethyl methylmalonate (in water)
waterN  Parameter: 17.68
sN Parameter: 0.50
*J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of 3-methyl acetylacetone (in DMSO)
DMSON  Parameter: 18.38
sN Parameter: 0.72
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of 3-methyl acetylacetone (in water)
waterN  Parameter: 14.33
sN Parameter: 0.69
***J. Am. Chem. Soc. 2003, 125, 12980-12986
DOI: 10.1021/ja036838e
image of molecule

anion of Meldrums acid (in DMSO)
DMSON  Parameter: 13.91
sN Parameter: 0.86
***Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

anion of dimedone (in DMSO)
DMSON  Parameter: 16.27
sN Parameter: 0.77
***Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

anion of acetylacetone (in DMSO)
DMSON  Parameter: 17.64
sN Parameter: 0.73
***Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

anion of ethyl acetylacetate (in DMSO)
DMSON  Parameter: 18.82
sN Parameter: 0.69
***Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

anion of malononitrile (in DMSO)
DMSON  Parameter: 19.36
sN Parameter: 0.67
***Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

anion of ethyl cyanoacetate (in DMSO)
DMSON  Parameter: 19.62
sN Parameter: 0.67
***Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

anion of diethyl malonate (in DMSO)
DMSON  Parameter: 20.22
sN Parameter: 0.65
***Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P