Ylides
For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
Found 30 Molecules.
| Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
|---|---|---|---|---|
 (4-Br-C6H4)-(CO)-CH=SMe2 | dichloromethane | N Parameter: 11.95 sN Parameter: 0.76 |  | Angew. Chem. Int. Ed. 2009, 48, 5034-5037 DOI: 10.1002/anie.200900933 |
 (4-Br-C6H4)-(CO)-CH=SMe2 (in DMSO) | DMSO | N Parameter: 13.78 sN Parameter: 0.72 | | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 |
 (4-Me2N-C6H4)-(CO)-CH=SMe2 (in DMSO) | DMSO | N Parameter: 15.68 sN Parameter: 0.65 | | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 |
 (4-MeO-C6H4)-(CO)-CH=SMe2 (in DMSO) | DMSO | N Parameter: 14.48 sN Parameter: 0.71 | | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 |
 (C6H5)-(CO)-CH=SMe2 (in DMSO) | DMSO | N Parameter: 13.95 sN Parameter: 0.69 | | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 |
 1-(3-chloropyridin-1-ium-1-yl)-2-oxo-2-phenylethan-1-ide (in DMSO) | DMSO | N Parameter: 17.98 sN Parameter: 0.63 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 1-(4-(dimethylamino)pyridin-1-ium-1-yl)-2-oxo-2-phenylethan-1-ide (in DMSO) | DMSO | N Parameter: 21.61 sN Parameter: 0.58 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 1-(isoquinolin-2-ium-2-yl)-2-oxo-2-phenylethan-1-ide (in DMSO) | DMSO | N Parameter: 20.08 sN Parameter: 0.57 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 2-(diethylamino)-2-oxo-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 27.45 sN Parameter: 0.38 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 2-ethoxy-2-oxo-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 26.71 sN Parameter: 0.37 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 2-oxo-1-(pyridin-1-ium-1-yl)propan-1-ide (in DMSO) | DMSO | N Parameter: 20.24 sN Parameter: 0.60 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 2-oxo-2-phenyl-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 19.46 sN Parameter: 0.58 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 2-oxo-2-phenyl-1-(quinolin-1-ium-1-yl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 19.38 sN Parameter: 0.50 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 6-methyl-3-(phenyl-l3-iodanylidene)dihydro-2H-pyran-2,4(3H)-dione (in CH2Cl2) | dichloromethane | N Parameter: 4.67 sN Parameter: 0.92 | | J. Am. Chem. Soc. 2016, 138, 10304-10313 DOI: 10.1021/jacs.6b05768 |
 cyano(pyridin-1-ium-1-yl)methanide (in DMSO) | DMSO | N Parameter: 25.94 sN Parameter: 0.42 | | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h |
 Dimedone iodonium ylide (in CH2Cl2) | dichloromethane | N Parameter: 6.18 sN Parameter: 0.81 | | J. Am. Chem. Soc. 2016, 138, 10304-10313 DOI: 10.1021/jacs.6b05768 |
 Me2S(O)=CH2 (in DMSO) | DMSO | N Parameter: 21.29 sN Parameter: 0.47 | | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 |
 Me2S=CH(4-CN-C6H4) (in DMSO) | DMSO | N Parameter: 21.07 sN Parameter: 0.68 | | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 |
 Me2S=CH(p-NO2-C6H4) (in DMSO) | DMSO | N Parameter: 18.42 sN Parameter: 0.65 | | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 |
 Me2S=CH-CN (in DMSO) | DMSO | N Parameter: 16.23 sN Parameter: 0.60 | | Chem. Eur. J. 2010, 16, 8610-8614 DOI: 10.1002/chem.201001455 |
 Me2S=CH-CO2Et (in DMSO) | DMSO | N Parameter: 15.85 sN Parameter: 0.61 | | Chem. Eur. J. 2010, 16, 8610-8614 DOI: 10.1002/chem.201001455 |
 Meldrum's acid iodonium ylide (in CH2Cl2) | dichloromethane | N Parameter: 4.36 sN Parameter: 1.06 | | J. Am. Chem. Soc. 2016, 138, 10304-10313 DOI: 10.1021/jacs.6b05768 |
 N,N-Dimethylbarbituric acid iodonium ylide (in CHCl2) | dichloromethane | N Parameter: 7.98 sN Parameter: 0.71 | | J. Am. Chem. Soc. 2016, 138, 10304-10313 DOI: 10.1021/jacs.6b05768 |
 Ph3P=C(CH3)-CO2Et | dichloromethane | N Parameter: 13.09 sN Parameter: 0.73 | | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 |
 Ph3P=CH-C(O)Me (in MeCN) | MeCN | N Parameter: 10.27 sN Parameter: 0.83 | | J. Am. Chem. Soc. 2016, 138, 11272-11281 DOI: 10.1021/jacs.6b06264 |
 Ph3P=CH-CHO (in MeCN) | MeCN | N Parameter: 9.09 sN Parameter: 0.74 | | J. Am. Chem. Soc. 2016, 138, 11272-11281 DOI: 10.1021/jacs.6b06264 |
 Ph3P=CH-CN | dichloromethane | N Parameter: 12.29 sN Parameter: 0.75 | | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 |
 Ph3P=CH-CO2Et | dichloromethane | N Parameter: 12.79 sN Parameter: 0.77 | | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 |
 Ph3P=CH-CO2Et (in DMSO) | DMSO | N Parameter: 12.21 sN Parameter: 0.62 | | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 |
 Ph3P=CH-COPh | dichloromethane | N Parameter: 9.54 sN Parameter: 0.97 | | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 |