Group of Pablo Docampo - Faculty for Chemistry and Pharmacy
Group of Pablo Docampo - Faculty for Chemistry and Pharmacy
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Address | Dr. Michiel L. Petrus Department Chemie, Haus E, Office: 3.039 Ludwig-Maximilians-Universität München Butenandtstr. 11 81377 München Germany |
| Phone | +49 (0)89 2180-77626 | |
| Room | E3.039 | |
| michiel.petrus@cup.uni-muenchen.de |
My research is mainly in the field of (perovskite) solar cells. I focus on the synthesis of low-cost organic hole transporting materials, the environmental impact, and the influence of moisture on the perovskite stability. Furthermore I study charge transporting properties in small-molecules, polymers and covalent organic frameworks.
In perovskite solar cells, expensive organic materials (such as Spiro-OMeTAD) are used to selectively extract the postive charges from the perovskite and transport these to the electrode. In our group, we developed low-cost hole transporting materials by using simple condensation chemistry in which water is the only side-product. In perovskite solar cells, our hole transporting materials show comparable performance to state-of-the-art material, however the estimated cost contribution is two orders of magnitude lower. In addition, as a result of the simple chemistry, also the environmental impact is reduced. The results have been published: J. Mater. Chem. A, 2015 and J. Mater. Chem. A, 2017. By using different linkage units in those small molecules, we moreover can easily tune the chemical and optoelectronic properties of these HTM as we have shown in our recent publication: Mol. Syst. Des. Eng., 2018.
The simplicity of Schiff base condensation chemistry is demonstrated in this video.
Organiser of the E-MRS Fall Meeting symposium 2016 "Organic solar cells including polymers, dyes or perovskites"
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New Generation Hole Transporting Materials for Perovskite Solar Cells: Amide-Based Small Molecules with Nonconjugated Backbones |
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Michiel L. Petrus Adv. Energy Mat, 2018, 1801605 |
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Hydrazone-based hole transporting material prepared via condensation chemistry as alternative for cross-coupling chemistry for perovskite solar cells |
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Michiel L. Petrus* Mol. Syst. Des. Eng., 2018, Advance Article |
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* These authors contributed equally to the work.
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Understanding the Role of Cesium and Rubidium Additives in Perovskite Solar Cells: Trap States, Charge Transport, and Recombination |
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Yinghong Hu Adv. Energy. Mater, 2018, ahead of print |
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[COVER IMAGE] Design Rules for the Preparation of Low-Cost Hole Transporting Materials for Perovskite Solar Cells with Moisture Barrier Properties |
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Michiel L. Petrus |
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Design Rules for the Preparation of Low-Cost Hole Transporting Materials for Perovskite Solar Cells with Moisture Barrier Properties |
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Michiel L. Petrus |
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Highly stable, phase pure Cs2AgBiBr6 double perovskite thin films for optoelectronic applications |
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Enrico Greul |
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Impact of Rubidium and Cesium Cations on the Moisture Stability of Multiple-Cation Mixed-Halide Perovskites |
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Yinghong Hu
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[COVER IMAGE] Perovskite Solar Cells: Capturing the Sun: A Review of the Challenges and Perspectives of Perovskite Solar Cells |
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Michiel L. Petrus* |
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Capturing the Sun: A Review of the Challenges and Perspectives of Perovskite Solar Cells |
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Michiel L. Petrus* |
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Charge Transfer from Methylammonium Lead Iodide Perovskite to Organic Transport Materials: Efficiencies, Transfer Rates, and Interfacial Recombination |
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Eline M. Hutter Adv. Energy. Mater. 2017, 1602349 |
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Directional Charge Carrier Transport in Oriented Benzodithiophene Covalent Organic Framework Thin Films |
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Dana D. Medina* ACS Nano, 2017, 11 (3), 2706-2713 |
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* These authors contributed equally to the work.
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The Influence of Water Vapor on the Stability and Processing of Hybrid Perovskite Solar Cells Made from Non-Stoichiometric Precursor Mixtures |
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Michiel L. Petrus* ChemSusChem, 2016, 9 (18), 2699-2707 |
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* These authors contributed equally to the work.
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Unconventional Thin Film Photovoltaics |
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Fabian Hanusch Unconventional Thin Film Photovoltaics, Chapter 2, 2016, 32-56 ISBN: 978-1-78262-293-2 |
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Hybrid Perovskite/Perovskite Heterojunction Solar Cells |
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Yinghong Hu |
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Recycling Perovskite Solar Cells to Avoid Lead Waste |
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Andreas Binek* |
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* These authors contributed equally to the work.
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Charge Transport Through Conjugated Azomethine-based Single Molecules for Optoelectronic Applications |
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Max Koole |
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A Low Cost Azomethine-Based Hole Transporting Material for Perovskite Photovoltaics |
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Michiel L. Petrus J. Mater. Chem. A, 2015, 3, 12159 (open Access) |
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Device Performance of Small-Molecule Azomethine-Based Bulk Heterojunction Solar Cells |
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Michiel L. Petrus |
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Correlating On-Substrate Prepared Electrochromes With Their Solution Processed Counterparts – Towards Validating Polyazomethines as Electrochromes in Functioning Devices |
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Michael Mulholland |
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Small-Molecule Azomethines: Organic Photovoltaics via Schiff Base Condensation Chemistry |
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Michiel L. Petrus J. Mater. Chem. A, 2014, 2 (25), 9474 (open access) |
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Conjugated poly(azomethine)s via simple one-step polycondensation chemistry: synthesis, thermal and optoelectronic properties |
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Michiel L. Petrus |
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Enantioselective Synthesis of syn- and anti-1,3-Aminoalcohols via β-Aminoketones and Subsequent Reduction/Dynamic Kinetic Asymmetric Transformation |
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R. Millet |
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