Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Electrophiles

Found 363 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

pop(tol)CH+
0E Parameter: 2.16
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

fc(ani)CH+
0E Parameter: -2.90
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

fc(Me)CH+
0E Parameter: -2.57
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

fc2CH+
0E Parameter: -8.54
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

C7H7+-Fe(CO)3
E Parameter: -3.49
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

C7H9+-Fe(CO)3
E Parameter: -9.21
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

C6H7+-Fe(CO)3
E Parameter: -7.76
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

C6H6OMe+-Fe(CO)3
E Parameter: -8.94
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

benzaldehyde-boron trichloride complex
E Parameter: 1.12
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

4-chlorobenzaldehyde-boron trichloride complex
E Parameter: 1.44
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

tropylium ion
0E Parameter: -3.72
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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propyn-1-ylium-Co2(CO)6
E Parameter: -0.84
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-phenyl-proyn-ylium-Co2(CO)6
E Parameter: -0.97
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

3-phenylpropyn-1-ylium-Co2(CO)6
E Parameter: -1.58
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6
E Parameter: -1.60
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3)
E Parameter: -6.19
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2-phenyl-1,3-dithiolan-2-ylium ion
0E Parameter: -5.91
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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2-phenyl-1,3-dithianylium ion
0E Parameter: -6.43
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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1,3-dithianylium ion
0E Parameter: -2.14
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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N-ethylidenecarbazolium ion
0E Parameter: 2.41
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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N-methylacridinium ion
0E Parameter: -7.15
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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dimethylmethyleneammonium ion
0E Parameter: -6.69
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methyl(phenyl)methyleneammonium ion
0E Parameter: -5.17
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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Vilsmeier ion
0E Parameter: -5.77
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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methoxy-phenylmethylium ion
0E Parameter: 2.97
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methoxy-(4-methoxyphenyl)methylium ion
0E Parameter: 0.14
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methoxy-(4-methylphenyl)methylium ion
0E Parameter: 1.90
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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Pd-allyl cation
E Parameter: -10.11
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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flavylium ion
0E Parameter: -3.45
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2-(4-methoxyphenyl)chromenylium ion
0E Parameter: -4.95
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1,1,3-triphenylallylium ion
0E Parameter: 0.98
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1,1-dianisyl-3-phenylallylium ion
0E Parameter: -2.67
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1,1-bis(4-dimethylaminophenyl)-3-phenylallylium ion
0E Parameter: -8.97
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1,1,3-tris(4-(dimethylamino)phenyl)allylium ion
0E Parameter: -9.84
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-phenylcyclopent-2-enylium ion
0E Parameter: 2.89
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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1-(4-chlorophenyl)cyclopent-2-enylium ion
0E Parameter: 3.20
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1,3-diphenylpropyn-1-ylium-Cr(CO)3
E Parameter: 1.07
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1,1,3-triphenylpropyn-1-ylium-Cr(CO)3
E Parameter: -0.25
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

ani(Br)2QM
0E Parameter: -8.63
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

ani(Ph)2QM
0E Parameter: -12.18
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

dma(Ph)2QM
0E Parameter: -13.39
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

tol(t-Bu)2QM
0E Parameter: -15.83
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

ani(t-Bu)2QM
E Parameter: -16.11
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

dma(t-Bu)2QM
E Parameter: -17.29
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

jul(t-Bu)2QM
0E Parameter: -17.90
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

Me2N+=CH-CH-Ph
0E Parameter: -9.20
***Angew. Chem. Int. Ed. 2008, 47, 8723-8726
DOI: 10.1002/anie.200802889
image of molecule

pyrN+=CH-CH-Ph
0E Parameter: -9.80
***Angew. Chem. Int. Ed. 2008, 47, 8723-8726
DOI: 10.1002/anie.200802889
image of molecule

pipN+=CH-CH-Ph
0E Parameter: -10.30
*Angew. Chem. Int. Ed. 2008, 47, 8723-8726
DOI: 10.1002/anie.200802889
image of molecule

(PhCH2)2N+=CH-CH-Ph
0E Parameter: -8.50
***Angew. Chem. Int. Ed. 2008, 47, 8723-8726
DOI: 10.1002/anie.200802889
image of molecule

Jorgensen/Hayashi-iminium ion
0E Parameter: -8.20
***Angew. Chem. Int. Ed. 2008, 47, 8723-8726
DOI: 10.1002/anie.200802889
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MacMillan-iminium ion (1st generation)
MeCNE Parameter: -7.37
***Angew. Chem. Int. Ed. 2011, 50, 9953-9956
DOI: 10.1002/anie.201103683
image of molecule

mor iminium
0E Parameter: -8.60
***Angew. Chem. Int. Ed. 2008, 47, 8723-8726
DOI: 10.1002/anie.200802889
image of molecule

MacMillan-iminium ion (2nd generation)
MeCNE Parameter: -5.52
***Angew. Chem. Int. Ed. 2011, 50, 9953-9956
DOI: 10.1002/anie.201103683
image of molecule

MacMillan-iminium ion (spiro)
MeCNE Parameter: -7.67
***Angew. Chem. Int. Ed. 2011, 50, 9953-9956
DOI: 10.1002/anie.201103683
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indolecarboxylate derived iminium ion
dichloromethaneE Parameter: -9.50
**Angew. Chem. Int. Ed. 2009, 48, 5034-5037
DOI: 10.1002/anie.200900933
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2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium
DMSOE Parameter: -11.52
***Angew. Chem. Int. Ed. 2012, 51, 5234-5238
DOI: 10.1002/anie.201109042
image of molecule

(S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium
dichloromethaneE Parameter: -6.00
**Angew. Chem. Int. Ed. 2013, 52, 7967-7971
DOI: 10.1002/anie.201301864
image of molecule

(S,E)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)-5-(3,4,5-trimethoxybenzyl)imidazolidin-1-ium
dichloromethaneE Parameter: -7.00
**Angew. Chem. Int. Ed. 2013, 52, 7967-7971
DOI: 10.1002/anie.201301864
image of molecule

ethenesulfonyl fluoride (ESF)
DMSOE Parameter: -12.09
***Angew. Chem. Int. Ed. 2016, 55, 12664-12667
DOI: 10.1002/anie.201601875
image of molecule

2-phenylethene-1-sulfonyl fluoride
DMSOE Parameter: -16.63
***Angew. Chem. Int. Ed. 2016, 55, 12664-12667
DOI: 10.1002/anie.201601875
image of molecule

N-(phenylsulfonyl)-N-((trifluoromethyl)thio)benzenesulfonamide
0E Parameter: -6.06
***Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

N-(trifluoromethyl)thio)phthalimide
0E Parameter: -11.92
***Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

N-(trifluoromethyl)thio)saccharin
0E Parameter: -6.48
***Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

N-(trifluoromethyl)thio)succinimide
0E Parameter: -12.56
***Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

N-(difluoromethyl)thio)phthalimide
0E Parameter: -11.86
***Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide
0E Parameter: -13.44
***Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

N-methyl-N-((trifluoromethyl)thio)-aniline
0E Parameter: -23.32
*Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

((2-phenylpropan-2-yl)oxy)(trifluoromethyl)sulfane
0E Parameter: -13.77
***Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane
0E Parameter: -14.52
***Angew. Chem. Int. Ed. 2018, 57, 12690-12695
DOI: 10.1002/anie.201805859
image of molecule

4-phenylbut-3-yn-2-one
0E Parameter: -16.90
-Angew. Chem. Int. Ed. 2019, 58, 17704-17708
DOI: 10.1002/anie.201909803
image of molecule

hex-3-yn-2-one
0E Parameter: -17.90
-Angew. Chem. Int. Ed. 2019, 58, 17704-17708
DOI: 10.1002/anie.201909803
image of molecule

butynone
0E Parameter: -16.60
-Angew. Chem. Int. Ed. 2019, 58, 17704-17708
DOI: 10.1002/anie.201909803
image of molecule

(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(4-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium
dichloromethaneE Parameter: -5.90
**Asian J. Org. Chem. 2014, 3, 550-555
DOI: 10.1002/ajoc.201402009
image of molecule

(S,E)-5-benzyl-1-((E)-3-(4-cyanophenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium
dichloromethaneE Parameter: -6.00
**Asian J. Org. Chem. 2014, 3, 550-555
DOI: 10.1002/ajoc.201402009
image of molecule

(S,E)-5-benzyl-1-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium
dichloromethaneE Parameter: -10.60
**Asian J. Org. Chem. 2014, 3, 550-555
DOI: 10.1002/ajoc.201402009
image of molecule

(S,E)-5-benzyl-2,2,3-trimethyl-4-oxo-1-((E)-3-(p-tolyl)allylidene)imidazolidin-1-ium
dichloromethaneE Parameter: -7.20
**Asian J. Org. Chem. 2014, 3, 550-555
DOI: 10.1002/ajoc.201402009
image of molecule

(S,E)-5-benzyl-1-((E)-3-(4-methoxyphenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium
dichloromethaneE Parameter: -8.00
**Asian J. Org. Chem. 2014, 3, 550-555
DOI: 10.1002/ajoc.201402009
image of molecule

(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(3-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium
dichloromethaneE Parameter: -6.10
**Asian J. Org. Chem. 2014, 3, 550-555
DOI: 10.1002/ajoc.201402009
image of molecule

(S,E)-5-((1H-indol-3-yl)methyl)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)imidazolidin-1-ium
dichloromethaneE Parameter: -7.30
**Asian J. Org. Chem. 2014, 3, 550-555
DOI: 10.1002/ajoc.201402009
image of molecule

(2S,5S)-5-benzyl-3-methyl-4-oxo-1-(3-phenylallylidene)-2-((E)-styryl)imidazolidin-1-ium
dichloromethaneE Parameter: -5.90
**Asian J. Org. Chem. 2014, 3, 550-555
DOI: 10.1002/ajoc.201402009
image of molecule

(ethene-1,1-diyldisulfonyl)dibenzene
DMSOE Parameter: -7.50
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

(2-phenylethene-1,1-diyldisulfonyl)dibenzene
DMSOE Parameter: -12.93
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

(2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene
DMSOE Parameter: -13.88
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline
DMSOE Parameter: -16.53
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide
DMSOE Parameter: -11.78
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide
DMSOE Parameter: -13.02
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide
DMSOE Parameter: -14.55
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

ethyl 3-nitro-1H-indole-1-carboxylate
0E Parameter: -14.10
**Chem. Commun. 2021, 57, 10071-10074
DOI: 10.1039/d1cc04074j
image of molecule

3-nitro-1-tosyl-1H-indole
0E Parameter: -14.87
***Chem. Commun. 2021, 57, 10071-10074
DOI: 10.1039/d1cc04074j
image of molecule

4-bromo-3-nitro-1-tosyl-1H-indole
0E Parameter: -14.60
**Chem. Commun. 2021, 57, 10071-10074
DOI: 10.1039/d1cc04074j
image of molecule

3,6-dinitro-1-tosyl-1H-indole
0E Parameter: -12.90
***Chem. Commun. 2021, 57, 10071-10074
DOI: 10.1039/d1cc04074j
image of molecule

4-nitrobenzodifuroxan (NBDF)
0E Parameter: -6.15
***Chem. Eur. J. 2007, 13, 8317-8324
DOI: 10.1002/chem.200700676
image of molecule

diethyl benzylidene malonate
0E Parameter: -20.55
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 4-nitrobenzylidene malonate
0E Parameter: -17.67
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 4-cyano-benzylidene malonate
0E Parameter: -18.06
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 3-chloro-benzylidene malonate
0E Parameter: -18.98
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 4-methyl-benzylidene malonate
0E Parameter: -21.11
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 4-methoxy-benzylidene malonate
0E Parameter: -21.47
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 4-(dimethylamino)benzylidene malonate
0E Parameter: -23.10
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate
0E Parameter: -23.40
*Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 2-((julolidine-9-yl)methylene)malonate
0E Parameter: -23.80
*Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

bh6a
E Parameter: -18.60
**Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
image of molecule

bh 6f
E Parameter: -18.90
**Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
image of molecule

bh 6i
E Parameter: -19.10
**Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
image of molecule

bh6j
E Parameter: -17.90
**Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
image of molecule

bh 6k
E Parameter: -18.20
*Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
image of molecule

bh 6l
E Parameter: -18.90
*Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
image of molecule

bh 6m
E Parameter: -17.30
*Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
image of molecule

1,2-diaza-1,3-diene 1a
DMSOE Parameter: -13.28
***Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1b
DMSOE Parameter: -13.90
***Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1c
DMSOE Parameter: -14.91
***Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1d
DMSOE Parameter: -15.38
***Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1e
MeOHE Parameter: -14.90
*Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1f
MeOHE Parameter: -15.30
*Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

dibenzyl azodicarboxylate
MeCNE Parameter: -8.89
***Chem. Eur. J. 2010, 16, 11670-11677
DOI: 10.1002/chem.201001598
image of molecule

diethyl azodicarboxylate
MeCNE Parameter: -10.15
***Chem. Eur. J. 2010, 16, 11670-11677
DOI: 10.1002/chem.201001598
image of molecule

diisopropyl azodicarboxylate
MeCNE Parameter: -10.71
***Chem. Eur. J. 2010, 16, 11670-11677
DOI: 10.1002/chem.201001598
image of molecule

di-tert-butyl azodicarboxylate
MeCNE Parameter: -12.23
***Chem. Eur. J. 2010, 16, 11670-11677
DOI: 10.1002/chem.201001598
image of molecule

9-phenyl-9H-fluoren-9-ylium
dichloromethaneE Parameter: 2.41
***Chem. Eur. J. 2017, 23, 623-630
DOI: 10.1002/chem.201603963
image of molecule

9-(4-methoxyphenyl)-9H-fluoren-9-ylium
dichloromethaneE Parameter: 0.85
***Chem. Eur. J. 2017, 23, 623-630
DOI: 10.1002/chem.201603963
image of molecule

9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium
dichloromethaneE Parameter: -4.51
***Chem. Eur. J. 2017, 23, 623-630
DOI: 10.1002/chem.201603963
image of molecule

methyl diazoacetate
0E Parameter: -18.50
***Chem. Eur. J. 2022, 28, e202201376
DOI: 10.1002/chem.202201376
image of molecule

dimethyl diazomalonate
0E Parameter: -18.20
***Chem. Eur. J. 2022, 28, e202201376
DOI: 10.1002/chem.202201376
image of molecule

(p-nitrophenyl)diazomethane
0E Parameter: -18.30
***Chem. Eur. J. 2022, 28, e202201376
DOI: 10.1002/chem.202201376
image of molecule

diphenyldiazomethane
0E Parameter: -21.40
-Chem. Eur. J. 2022, 28, e202201376
DOI: 10.1002/chem.202201376
image of molecule

(E)-6-(4-nitrobenzylidene)benzo[d][1,3]dioxol-5(6H)-one
0E Parameter: -13.15
***Chem. Eur. J. 2024, , e202403785
DOI: 10.1002/chem.202403785
image of molecule

(E)-6-(4-(trifluoromethyl)benzylidene)benzo[d][1,3]dioxol-5(6H)-one
0E Parameter: -13.54
***Chem. Eur. J. 2024, , e202403785
DOI: 10.1002/chem.202403785
image of molecule

(E)-6-(3-fluorobenzylidene)benzo[d][1,3]dioxol-5(6H)-one
0E Parameter: -14.00
***Chem. Eur. J. 2024, , e202403785
DOI: 10.1002/chem.202403785
image of molecule

(E)-6-(4-chlorobenzylidene)benzo[d][1,3]dioxol-5(6H)-one
0E Parameter: -13.99
***Chem. Eur. J. 2024, , e202403785
DOI: 10.1002/chem.202403785
image of molecule

(E)-6-benzylidenebenzo[d][1,3]dioxol-5(6H)-one
0E Parameter: -14.47
***Chem. Eur. J. 2024, , e202403785
DOI: 10.1002/chem.202403785
image of molecule

(E)-6-(4-methylbenzylidene)benzo[d][1,3]dioxol-5(6H)-one
0E Parameter: -14.85
***Chem. Eur. J. 2024, , e202403785
DOI: 10.1002/chem.202403785
image of molecule

(E)-6-(4-methoxybenzylidene)benzo[d][1,3]dioxol-5(6H)-one
0E Parameter: -15.20
***Chem. Eur. J. 2024, , e202403785
DOI: 10.1002/chem.202403785
image of molecule

(E)-6-(4-(dimethylamino)benzylidene)benzo[d][1,3]dioxol-5(6H)-one
0E Parameter: -16.07
***Chem. Eur. J. 2024, , e202403785
DOI: 10.1002/chem.202403785
image of molecule

3-methylcyclopentenone
DMSOE Parameter: -28.90
*Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

2-methylcyclopentenone
DMSOE Parameter: -22.10
***Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

cyclopentenone
DMSOE Parameter: -20.60
***Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

furan-2(5H)-one
DMSOE Parameter: -20.70
***Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

2-methylcyclohexenone
DMSOE Parameter: -27.50
*Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

cyclohexenone
DMSOE Parameter: -22.10
***Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

dihydro-2H-pyran-2-one
DMSOE Parameter: -21.80
**Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

3-methylenetetrahydropyran-2-one
DMSOE Parameter: -19.50
***Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

3-methylenedihydrofuranone
DMSOE Parameter: -19.40
***Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

3-methylcyclohexenone
DMSOE Parameter: -29.60
*Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

cycloheptenone
DMSOE Parameter: -22.00
***Chem. Sci. 2021, 12, 4850-4865
DOI: 10.1039/D0SC06628A
image of molecule

2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone
0E Parameter: -11.87
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone
0E Parameter: -16.38
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone
0E Parameter: -17.18
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone
0E Parameter: -16.36
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone
0E Parameter: -15.03
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone
0E Parameter: -14.50
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone
0E Parameter: -14.36
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

(4-MeO)-tritylium ion
E Parameter: -1.59
-Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910
image of molecule

(4-F)-tritylium ion
E Parameter: 0.35
*Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910
image of molecule

(4-F)2-tritylium ion
E Parameter: 0.17
*Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910
image of molecule

(4-F)3-tritylium ion
E Parameter: 0.05
*Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910
image of molecule

(3-F)-tritylium ion
E Parameter: 1.01
*Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910
image of molecule

(3-F)2-tritylium ion
E Parameter: 1.54
*Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910
image of molecule

(3-F)3-tritylium ion
E Parameter: 2.07
*Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910
image of molecule

(3-F)4-tritylium ion
E Parameter: 2.54
*Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910
image of molecule

maleic anhydride
DMSOE Parameter: -11.31
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
image of molecule

N-methyl maleimide
DMSOE Parameter: -14.07
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
image of molecule

fumaronitrile
DMSOE Parameter: -15.71
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
image of molecule

diethyl fumarate
DMSOE Parameter: -17.79
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
image of molecule

diethyl maleate
DMSOE Parameter: -19.49
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
image of molecule

(E)-2-(tert-butyl)-3-(4-methylbenzylidene)-3H-indol-1-ium
dichloromethaneE Parameter: -5.06
*Eur. J. Org. Chem. 2016, , 4050-4058
DOI: 10.1002/ejoc.201600572
image of molecule

2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one
DMSOE Parameter: -11.68
***Eur. J. Org. Chem. 2020, , 3812-3817
DOI: 10.1002/ejoc.202000295
image of molecule

Umemoto I (triflate)
0E Parameter: -13.08
***Eur. J. Org. Chem. 2024, 27, e202400085
DOI: 10.1002/ejoc.202400085
image of molecule

Umemoto I (tetrafluoroborate)
0E Parameter: -13.39
***Eur. J. Org. Chem. 2024, 27, e202400085
DOI: 10.1002/ejoc.202400085
image of molecule

Umemoto II (triflate)
0E Parameter: -12.80
***Eur. J. Org. Chem. 2024, 27, e202400085
DOI: 10.1002/ejoc.202400085
image of molecule

dicarbonyl(cyclopentadienyl)propene-iron(II)
E Parameter: -11.20
***Helv. Chim. Acta 2005, 88, 1754-1768
DOI: 10.1002/hlca.200590137
image of molecule

benzhydrylium ion Ph2CH+
0E Parameter: 5.47
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(pcp)2CH+
0E Parameter: 5.48
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

pfp(Ph)CH+
0E Parameter: 5.20
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(fur)2CH+
0E Parameter: -1.36
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(ani)2CH+
0E Parameter: 0.00
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(tol)2CH+
0E Parameter: 3.63
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(pfa)2CH+
0E Parameter: -3.14
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(mfa)2CH+
0E Parameter: -3.85
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(dpa)2CH+
0E Parameter: -4.72
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(mor)2CH+
0E Parameter: -5.53
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(mpa)2CH+
0E Parameter: -5.89
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(dma)2CH+
0E Parameter: -7.02
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(pyr)2CH+
0E Parameter: -7.69
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(thq)2CH+
0E Parameter: -8.22
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(ind)2CH+
0E Parameter: -8.76
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(jul)2CH+
0E Parameter: -9.45
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(lil)2CH+
0E Parameter: -10.04
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

ani(pop)CH+
0E Parameter: 0.61
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

ani(Ph)CH+
0E Parameter: 2.11
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

ani(tol)CH+
0E Parameter: 1.48
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

pop(Ph)CH+
0E Parameter: 2.90
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

tol(Ph)CH+
0E Parameter: 4.43
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(pfp)2CH+
0E Parameter: 5.01
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

fc(Ph)CH+
0E Parameter: -2.64
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

tritylium ion (Ph3C+)
0E Parameter: 0.51
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-CF3)2-tritylium ion
E Parameter: 2.28
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(3-Cl)3-tritylium ion
E Parameter: 1.99
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-CF3)-tritylium ion
E Parameter: 1.33
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(3-Cl)-tritylium ion
E Parameter: 1.06
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(3-CF3)-tritylium ion
E Parameter: 1.18
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-Me)-tritylium ion
E Parameter: -0.13
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-Me)2-tritylium ion
E Parameter: -0.70
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-Me)3-tritylium ion
E Parameter: -1.21
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-MeO,3-OMe)-tritylium ion
E Parameter: -1.62
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-OMe,3-Me)-tritylium ion
E Parameter: -1.84
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-MeO,4-Me)-tritylium ion
E Parameter: -2.13
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-MeO)2-tritylium ion
E Parameter: -3.04
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-MeO)3-tritylium ion
E Parameter: -4.35
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-NMe2)-tritylium ion
E Parameter: -7.93
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-NMe2)2-tritylium ion (= Malachite green)
E Parameter: -10.29
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(4-NMe2)3-tritylium ion (= Crystal violet)
E Parameter: -11.26
-J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

(E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)
DMSOE Parameter: -17.33
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)
DMSOE Parameter: -17.64
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-1,3-diphenylprop-2-en-1-one (in DMSO)
DMSOE Parameter: -19.39
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

(E)-4-(4-nitrophenyl)but-3-en-2-one (in DSMO)
DMSOE Parameter: -19.36
*J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-4-methyl-1-(4-nitrophenyl)pent-1-en-3-one (in DMSO)
DMSOE Parameter: -19.17
*J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one
DMSOE Parameter: -19.15
*J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

3-chloro-benzaldehyde (in DMSO)
DMSO-J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

3-fluoro-benzaldehyde (in DMSO)
DMSO-J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

3-methoxy-benzaldehyde (in DMSO)
DMSO-J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

4-fluoro-benzaldehyde (in DMSO)
DMSO-J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

benzaldehyde (in DMSO)
DMSOE Parameter: -12.90
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

hexanal (in DMSO)
DMSO-J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

butanal (in DMSO)
DMSO-J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

cinnamaldehyde (in DMSO)
DMSO-J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

p-nitro-cinnamaldehyde (in DMSO)
DMSO-J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-N-benzylidene-4-methylbenzenesulfonamide (in DMSO)
DMSOE Parameter: -11.50
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-N-(4-methoxybenzylidene)-4-methylbenzenesulfonamide (in DMSO)
DMSOE Parameter: -13.05
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-N-(4-(dimethylamino)benzylidene)-4-methylbenzenesulfonamide (in DMSO)
DMSOE Parameter: -15.09
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-tert-butyl benzylidenecarbamate (in DMSO)
DMSOE Parameter: -14.22
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-N-benzylidene-P,P-diphenylphosphinic amide
DMSOE Parameter: -15.89
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(fur)(ani)CH+
0E Parameter: -0.81
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(mfp)PhCH+
0E Parameter: 6.23
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(tfm)PhCH+
0E Parameter: 6.70
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(dfp)PhCH+
0E Parameter: 6.74
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(mfp)2CH+
0E Parameter: 6.87
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(dfp)(mfp)CH+
0E Parameter: 7.52
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(tfm)2CH+
0E Parameter: 7.96
**J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(dfp)2CH+
0E Parameter: 8.02
*J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

(Ftol)2CH+
0E Parameter: 5.24
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

PhCH=N+Me2 (in MeCN)
MeCNE Parameter: -9.27
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

pTolCH=N+CH2 (in MeCN)
MeCNE Parameter: -9.64
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

p-AniCH=N+Me2 (in MeCN)
MeCNE Parameter: -10.69
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

PhCH=N+(CH2)4 (in MeCN)
MeCNE Parameter: -9.35
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

PhCH=N+(CH2)5 (in MeCN)
MeCNE Parameter: -9.60
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

p-CF3-C6H4-CH=N+Me2 (in MeCN)
MeCNE Parameter: -8.34
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ)
MeCNE Parameter: -3.66
***J. Am. Chem. Soc. 2013, 135, 12377-12387
DOI: 10.1021/ja405890d
image of molecule

p-quinone (C-H)
0E Parameter: -16.19
**J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

2,5-dichloroquinone (C-H)
0E Parameter: -12.28
***J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

2,5-dichloroquinone (C-Cl)
0E Parameter: -16.11
***J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

p-chloranil (C=O)
0E Parameter: -12.13
***J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

p-chloranil (C-Cl)
0E Parameter: -13.84
***J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

p-fluoranil (C=O)
0E Parameter: -9.37
***J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

p-fluoranil (C-F)
0E Parameter: -11.12
***J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

o-chloranil (C=O)
0E Parameter: -8.77
***J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

o-chloranil (C-Cl)
0E Parameter: -12.02
***J. Am. Chem. Soc. 2014, 136, 11499-11512
DOI: 10.1021/ja505613b
image of molecule

(E)-4-phenylbut-3-en-2-one (in DMSO)
DMSOE Parameter: -23.01
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

cinnamonitrile (in DMSO)
DMSOE Parameter: -24.60
*J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

methyl prop-2-enoate (in DMSO)
DMSOE Parameter: -18.84
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

ethyl prop-2-enoate (in DMSO)
DMSOE Parameter: -19.07
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

tert-butyl prop-2-enoate (in DMSO)
DMSOE Parameter: -20.22
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

N,N-dimethylprop-2-enamide (in DMSO)
DMSOE Parameter: -23.54
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

ethenylsulfonylbenzene (in DMSO)
DMSOE Parameter: -18.36
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

acrylonitrile (in DMSO)
DMSOE Parameter: -19.05
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

but-3-en-2-one (in DMSO)
DMSOE Parameter: -16.76
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

1-phenylprop-2-en-1-one (in DMSO)
DMSOE Parameter: -15.25
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

ethyl 2-methylprop-2-enoate (in DMSO)
DMSOE Parameter: -22.77
**J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

ethyl (E)-but-2-enoate (in DMSO)
DMSOE Parameter: -23.59
**J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

ethyl cinnamate (in DMSO)
DMSOE Parameter: -24.52
**J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

(E)-1-methyl-4-(styrylsulfonyl)benzene (in DMSO)
DMSOE Parameter: -24.69
**J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

cyclobutanone (in DMSO)
DMSOE Parameter: -17.50
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

cyclopentanone (in DMSO)
DMSOE Parameter: -21.00
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

cyclohexanone (in DMSO)
DMSOE Parameter: -19.90
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

cycloheptanone (in DMSO)
DMSOE Parameter: -22.10
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

1-methylpiperidin-4-one (in DMSO)
DMSOE Parameter: -18.40
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

oxan-4-one (in DMSO)
DMSOE Parameter: -17.90
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

thian-4-one (in DMSO)
DMSOE Parameter: -16.90
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

1,4-dioxaspiro[4.5]decan-8-one (in DMSO)
DMSOE Parameter: -18.20
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

pentan-2-one (in DMSO)
DMSOE Parameter: -22.30
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

1-methylsulfanylpropan-2-one (in DMSO)
DMSOE Parameter: -15.60
*J. Am. Chem. Soc. 2018, 140, 5500-5515
DOI: 10.1021/jacs.8b01657
image of molecule

N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate
0E Parameter: -10.46
***J. Am. Chem. Soc. 2018, 140, 11474-11486
DOI: 10.1021/jacs.8b07147
image of molecule

N-fluoro-2,6-dichloropyridinium tetrafluoroborate
0E Parameter: -5.29
***J. Am. Chem. Soc. 2018, 140, 11474-11486
DOI: 10.1021/jacs.8b07147
image of molecule

Selectfluor
0E Parameter: -5.20
***J. Am. Chem. Soc. 2018, 140, 11474-11486
DOI: 10.1021/jacs.8b07147
image of molecule

NFSI
MeCNE Parameter: -8.44
***J. Am. Chem. Soc. 2018, 140, 11474-11486
DOI: 10.1021/jacs.8b07147
image of molecule

N-fluoropyridinium tetrafluoroborate
0E Parameter: -9.89
***J. Am. Chem. Soc. 2018, 140, 11474-11486
DOI: 10.1021/jacs.8b07147
image of molecule

phenyl isocyanate
MeCNE Parameter: -15.38
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
image of molecule

p-tosyl isocyanate
MeCNE Parameter: -7.69
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
image of molecule

phenyl isothiocyanate
DMSOE Parameter: -18.15
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
image of molecule

p-nitrophenyl isothiocyanate
DMSOE Parameter: -15.89
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
image of molecule

diphenylcarbodiimide
DMSOE Parameter: -20.14
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
image of molecule

carbon disulfide
DMSOE Parameter: -17.70
***J. Am. Chem. Soc. 2020, 142, 8383-8402
DOI: 10.1021/jacs.0c01960
image of molecule

benzylidenemalononitrile
0E Parameter: -9.42
***J. Org. Chem. 2003, 68, 6880-6886
DOI: 10.1021/jo0344182
image of molecule

p-(methoxy)benzylidenemalononitrile
0E Parameter: -10.80
***J. Org. Chem. 2003, 68, 6880-6886
DOI: 10.1021/jo0344182
image of molecule

p-(dimethylamino)benzylidenemalononitrile
0E Parameter: -13.30
***J. Org. Chem. 2003, 68, 6880-6886
DOI: 10.1021/jo0344182
image of molecule

4,6-dinitrobenzofuroxan
0E Parameter: -5.06
***J. Org. Chem. 2006, 71, 9088-9095
DOI: 10.1021/jo0614339
image of molecule

1,3,5-trinitrobenzene
0E Parameter: -13.19
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

6-nitro-tetrazolo[1,5a]pyridine
0E Parameter: -9.05
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

4-nitro-6-(trifluoromethylsulfonyl)benzofuroxan
0E Parameter: -4.91
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

4,6-dinitrotetrazolopyridine
0E Parameter: -4.67
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

4,6-dinitrobenzofurazan
0E Parameter: -5.46
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

2,4-dinitrothiophene
0E Parameter: -12.33
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

6-cyano-4-nitrobenzofuroxan
0E Parameter: -7.01
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

4-cyano-6-nitro-benzofuroxane
0E Parameter: -6.41
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

4-aza-6-nitrobenzofuroxan
0E Parameter: -5.86
***J. Org. Chem. 2005, 70, 6242-6253
DOI: 10.1021/jo0505526
image of molecule

aniBBS
0E Parameter: -10.37
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
image of molecule

dmaBBS
0E Parameter: -12.76
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
image of molecule

julBBS
0E Parameter: -13.84
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
image of molecule

dma(S)BBS
0E Parameter: -10.73
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
image of molecule

jul(S)BBS
0E Parameter: -11.89
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
image of molecule

benzylidene-Meldrum's acid
0E Parameter: -9.15
***J. Org. Chem. 2008, 73, 2738-2745
DOI: 10.1021/jo702590s
image of molecule

p-(methoxy)benzylidene Meldrum's acid
0E Parameter: -10.28
***J. Org. Chem. 2008, 73, 2738-2745
DOI: 10.1021/jo702590s
image of molecule

p-(dimethylamino)benzylidene Meldrum's acid
0E Parameter: -12.76
***J. Org. Chem. 2008, 73, 2738-2745
DOI: 10.1021/jo702590s
image of molecule

jul Meldrum's acid
0E Parameter: -13.97
***J. Org. Chem. 2008, 73, 2738-2745
DOI: 10.1021/jo702590s
image of molecule

diarylallylium ion (3,3-F2)2
E Parameter: 6.11
***J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

diarylallylium ion (3-F)2
E Parameter: 4.15
**J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

diarylallylium ion (4-Br)2
E Parameter: 2.85
***J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

diarylallylium ion (4-Cl)2
E Parameter: 2.69
*J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

diphenylallylium ion
E Parameter: 2.70
***J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

di-p-tolyl-allylium ion
E Parameter: 1.23
***J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

di-p-anisyl-allylium ion
E Parameter: -1.45
***J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

diarylallylium ion (4-NMe2)2
E Parameter: -7.50
***J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

bis(julidin-9-yl)allylium ion
E Parameter: -9.78
***J. Org. Chem. 2011, 76, 9391-9408
DOI: 10.1021/jo201668w
image of molecule

4-methoxy-<i>trans-beta</i>-nitrostyrene
E Parameter: -14.70
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

4-methyl-<i>trans-beta</i>-nitrostyrene
E Parameter: -14.23
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

<i>trans-beta</i>-nitrostyrene
E Parameter: -13.85
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

4-bromo-<i>trans-beta</i>-nitrostyrene
E Parameter: -13.37
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

4-cyano-<i>trans-beta</i>-nitrostyrene
E Parameter: -12.61
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

4-nitro-<i>trans-beta</i>-nitrostyrene
E Parameter: -12.37
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

3-benzylidene-1-methyl-3H-indol-1-ium ion
0E Parameter: -1.80
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion
0E Parameter: -2.19
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom
0E Parameter: -3.02
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion
0E Parameter: -6.26
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

1-methyl-3-((julolidin-9-yl)methylene)-3H-indol-1-ium ion
0E Parameter: -7.79
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

(E)-2-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion
0E Parameter: -5.15
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

(E)-1,2-dimethyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion
0E Parameter: -5.05
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

(E)-3-benzylidene-1,2-dimethyl-3H-indol-1-ium ion
0E Parameter: -4.96
**J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

bis(1-methylindol-3-yl)methylium ion
0E Parameter: -5.99
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

bis(5-methoxy-1-methylindol-3-yl)methylium ion
0E Parameter: -6.90
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

bis(1,2-dimethylindol-3-yl)methylium ion
0E Parameter: -10.23
***J. Org. Chem. 2015, 80, 8643-8656
DOI: 10.1021/acs.joc.5b01298
image of molecule

5-methoxyfuroxano[3,4-d]pyrimidine
0E Parameter: -8.37
***J. Phys. Org. Chem. 2003, 16, 431-437
DOI: 10.1002/poc.606
image of molecule

dibenzo[a,d]tropylium ion
dichloromethaneE Parameter: -0.63
-Liebigs Ann. 1995, , 2005-2009
DOI: 10.1002/jlac.1995199511281
image of molecule

(2,4,6-trimethylphenyl)ethylium ion
0E Parameter: 6.04
*Macromolecules 2005, 38, 33-40
DOI: 10.1021/ma048389o
image of molecule

1,3-bis(2,4,6-trimethylphenyl)but-1-ylium ion
0E Parameter: 6.16
*Macromolecules 2005, 38, 33-40
DOI: 10.1021/ma048389o
image of molecule

cumyl cation
E Parameter: 5.74
***Macromolecules 2010, 43, 1719-1723
DOI: 10.1021/ma9024569
image of molecule

2-(p-(dimethylamino)benzylidene)-indan-1,3-dione
0E Parameter: -13.56
***Org. Biomol. Chem. 2007, 5, 3020-3026
DOI: 10.1039/b708025e
image of molecule

2-(p-methoxybenzylidene)-indan-1,3-dione
0E Parameter: -11.32
***Org. Biomol. Chem. 2007, 5, 3020-3026
DOI: 10.1039/b708025e
image of molecule

2-benzylidene-indan-1,3-dione
0E Parameter: -10.11
***Org. Biomol. Chem. 2007, 5, 3020-3026
DOI: 10.1039/b708025e
image of molecule

jul-indan-1,3-dione
0E Parameter: -14.68
***Org. Biomol. Chem. 2007, 5, 3020-3026
DOI: 10.1039/b708025e
image of molecule

2,3,4,5,6,6-hexachlorocyclohexa-2,4-dien-1-one
MeCNE Parameter: -6.75
***Org. Lett. 2010, 12, 2238-2241
DOI: 10.1021/ol100592j
image of molecule

5,7,7-trichloro-8(7H)-quinolinone
MeCNE Parameter: -10.48
***Org. Lett. 2010, 12, 2238-2241
DOI: 10.1021/ol100592j
image of molecule

2,2,4-trichloro-1(2H)-naphthalenone
MeCNE Parameter: -11.24
***Org. Lett. 2010, 12, 2238-2241
DOI: 10.1021/ol100592j
image of molecule

(E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one
DMSOE Parameter: -17.00
***Org. Lett. 2020, 22, 2182-2186
DOI: 10.1021/acs.orglett.0c00338
image of molecule

E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one
DMSOE Parameter: -16.84
***Org. Lett. 2020, 22, 2182-2186
DOI: 10.1021/acs.orglett.0c00338
image of molecule

(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one
DMSOE Parameter: -16.25
***Org. Lett. 2020, 22, 2182-2186
DOI: 10.1021/acs.orglett.0c00338
image of molecule

(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one
DMSOE Parameter: -17.42
***Org. Lett. 2020, 22, 2182-2186
DOI: 10.1021/acs.orglett.0c00338
image of molecule

[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph)
E Parameter: -14.14
***Organometallics 2012, 31, 2416-2424
DOI: 10.1021/om3000357
image of molecule

[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl)
E Parameter: -14.21
***Organometallics 2012, 31, 2416-2424
DOI: 10.1021/om3000357
image of molecule

[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl)
E Parameter: -14.46
***Organometallics 2012, 31, 2416-2424
DOI: 10.1021/om3000357
image of molecule

2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium
DMSOE Parameter: -10.09
***Top. Catal. 2018, 61, 585-590
DOI: 10.1007/s11244-018-0914-5
image of molecule

1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium
DMSOE Parameter: -11.80
***Top. Catal. 2018, 61, 585-590
DOI: 10.1007/s11244-018-0914-5
image of molecule

2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium
DMSOE Parameter: -11.48
***Top. Catal. 2018, 61, 585-590
DOI: 10.1007/s11244-018-0914-5
image of molecule

2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium
DMSOE Parameter: -11.79
***Top. Catal. 2018, 61, 585-590
DOI: 10.1007/s11244-018-0914-5
image of molecule

2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium
DMSOE Parameter: -12.02
***Top. Catal. 2018, 61, 585-590
DOI: 10.1007/s11244-018-0914-5