Details of Molecule (4-MeO)-tritylium ion
For reactivities of structurally related compounds go to:
Electrophiles » C-Electrophiles » Carbocations » Triarylcarbenium Ions
| Structure |
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| Molecule class | Electrophiles » C-Electrophiles » Carbocations » Triarylcarbenium Ions |
| Quality |
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| Parameters |
E Parameter: -1.59 |
| Comment | E was determined from and for reactions with n-nucleophiles (not reference nucleophiles). E must not be used for predicting reactivitites toward pi-nucleophiles. The previously reported value of E = –1.87 (JACS 2003, 125, 286.) was based on only two reactions and should be revised. |
| Reference |
Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 |