Other solvents (pure or mixtures)
For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles » Alcohols and aqueous solvents
Found 11 Molecules.
Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
---|---|---|---|---|
H2O (in water) | water | N Parameter: 5.20 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
10% water/90% acetone (v/v) | water-acetone mix | N Parameter: 5.70 sN Parameter: 0.85 | Angew. Chem. Int. Ed. 2004, 43, 2302-2305 DOI: 10.1002/anie.200353468 | |
20% water/80% acetone (v/v) | water-acetone mix | N Parameter: 5.77 sN Parameter: 0.87 | Angew. Chem. Int. Ed. 2004, 43, 2302-2305 DOI: 10.1002/anie.200353468 | |
methanol | MeOH | N Parameter: 7.54 sN Parameter: 0.92 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
ethanol | EtOH | N Parameter: 7.44 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
91% n-propanol/9% MeCN (v/v) | nPrOH-MeCN mix | N Parameter: 7.05 sN Parameter: 0.80 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
91% propan-2-ol/9% MeCN (v/v) | iPrOH-MeCN mix | N Parameter: 6.49 sN Parameter: 0.96 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
DMSO (O attack) | DMSO | N Parameter: 11.30 sN Parameter: 0.74 | J. Am. Chem. Soc. 2009, 131, 11392-11401 DOI: 10.1021/ja903207b | |
trifluoroethanol | TFE | N Parameter: 1.11 sN Parameter: 0.96 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
isopropanol (in MeCN) | MeCN | N Parameter: 6.82 sN Parameter: 0.70 | Bull. Chem. Soc. Jpn. 2018, 91, 523-530 DOI: 10.1246/bcsj.20170360 | |
tert-butanol (in MeCN) | MeCN | N Parameter: 5.35 sN Parameter: 0.72 | Bull. Chem. Soc. Jpn. 2018, 91, 523-530 DOI: 10.1246/bcsj.20170360 |