Warning (2): unserialize() [function.unserialize]: Extra data starting at offset 3079 of 6170 bytes [CORE/cake/libs/cache/file.php, line 190]

                $data = str_replace('\\\\\\\\', '\\', $data);
            }
            $data = unserialize((string)$data);

unserialize - [internal], line ??
FileEngine::read() - CORE/cake/libs/cache/file.php, line 190
Cache::read() - CORE/cake/libs/cache.php, line 362
DataSource::__cacheDescription() - CORE/cake/libs/model/datasources/datasource.php, line 475
DataSource::describe() - CORE/cake/libs/model/datasources/datasource.php, line 278
DboMysqlBase::describe() - CORE/cake/libs/model/datasources/dbo/dbo_mysql.php, line 120
Model::schema() - CORE/cake/libs/model/model.php, line 938
Model::setSource() - CORE/cake/libs/model/model.php, line 789
Model::__construct() - CORE/cake/libs/model/model.php, line 483
ClassRegistry::init() - CORE/cake/libs/class_registry.php, line 142
Model::__constructLinkedModel() - CORE/cake/libs/model/model.php, line 667
Model::__createLinks() - CORE/cake/libs/model/model.php, line 638
Model::__construct() - CORE/cake/libs/model/model.php, line 491
ClassRegistry::init() - CORE/cake/libs/class_registry.php, line 142
Controller::loadModel() - CORE/cake/libs/controller/controller.php, line 634
Controller::constructClasses() - CORE/cake/libs/controller/controller.php, line 501
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 186
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171

Details of Molecule ((4-methoxyphenyl)sulfonyl)(pyridin-4-yl)amide (Ph4P+) (in CH2Cl2)

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Pyridines, Quinolines etc.

go back to last page

Structure
Molecule class	Nucleophiles » N-Nucleophiles » Pyridines, Quinolines etc.
Quality
Parameters	N Parameter: 19.63 s_N Parameter: 0.65
Comment	N and s_N were determined with reference electrophiles (benzhydrylium ions) at a constant ionic strength I = 1.0 mM and corrected for the free anion concentration; counterion is a triple ion of [(Ph₄P⁺)₂(Nuc^-)]⁺.
Sum formula	C12H11N2O3S-
Solvent	dichloromethane
Reference	J. Am. Chem. Soc. 2025, 147, 5043-5050 DOI: 10.1021/jacs.4c14825