Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Peroxy anions

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles
Found 16 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

2-phenylperoxyacetate (in H2O)
waterN  Parameter: 15.63
sN Parameter: 0.56
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

3,5-dichloroperoxybenzoate (in H2O)
waterN  Parameter: 17.93
sN Parameter: 0.50
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

3-chloro-4-methoxyperoxybenzoate (in H2O)
waterN  Parameter: 18.56
sN Parameter: 0.48
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

3-chloroperoxybenzoate (in H2O)
waterN  Parameter: 18.19
sN Parameter: 0.47
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

4-fluoroperoxybenzoate (in H2O)
waterN  Parameter: 17.99
sN Parameter: 0.47
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

4-methoxyperoxybenzoate (in H2O)
waterN  Parameter: 17.84
sN Parameter: 0.46
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

4-nitroperoxybenzoate (in H2O)
waterN  Parameter: 17.43
sN Parameter: 0.50
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

beta-piperidinium-peroxypropionate
waterN  Parameter: 13.94
sN Parameter: 0.62
***Eur. J. Org. Chem. 2018, , 6010-6017
DOI: 10.1002/ejoc.201801158
image of molecule

cumene peroxy anion (in H2O)
waterN  Parameter: 13.92
sN Parameter: 0.61
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

HOO- (in water)
waterN  Parameter: 15.40
sN Parameter: 0.55
***J. Am. Chem. Soc. 2003, 125, 286-295
DOI: 10.1021/ja021010y
image of molecule

magnesium 2-carboperoxybenzoate (in H2O)
waterN  Parameter: 18.43
sN Parameter: 0.46
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

peroxy-beta-alanate
waterN  Parameter: 14.07
sN Parameter: 0.56
***Eur. J. Org. Chem. 2018, , 6010-6017
DOI: 10.1002/ejoc.201801158
image of molecule

peroxy-GABA
waterN  Parameter: 14.33
sN Parameter: 0.57
***Eur. J. Org. Chem. 2018, , 6010-6017
DOI: 10.1002/ejoc.201801158
image of molecule

peroxybenzoate (in H2O)
waterN  Parameter: 18.57
sN Parameter: 0.43
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

phthalimidoperoxyhexanoate (in H2O)
waterN  Parameter: 16.02
sN Parameter: 0.54
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086
image of molecule

t-butylperoxy anion (in H2O)
waterN  Parameter: 14.29
sN Parameter: 0.51
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
DOI: 10.1002/anie.201707086