Warning (2): unserialize() [function.unserialize]: Extra data starting at offset 120 of 134 bytes [CORE/cake/libs/cache/file.php, line 190]
Code
                $data = str_replace('\\\\\\\\', '\\', $data);
            }
            $data = unserialize((string)$data);
unserialize - [internal], line ??
FileEngine::read() - CORE/cake/libs/cache/file.php, line 190
Cache::read() - CORE/cake/libs/cache.php, line 362
DataSource::listSources() - CORE/cake/libs/model/datasources/datasource.php, line 237
DboMysqli::listSources() - CORE/cake/libs/model/datasources/dbo/dbo_mysqli.php, line 146
Model::setSource() - CORE/cake/libs/model/model.php, line 777
Model::__construct() - CORE/cake/libs/model/model.php, line 483
ClassRegistry::init() - CORE/cake/libs/class_registry.php, line 142
Controller::loadModel() - CORE/cake/libs/controller/controller.php, line 634
Controller::constructClasses() - CORE/cake/libs/controller/controller.php, line 501
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 186
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171
[main] - APP/webroot/index.php, line 83

Warning (2): unserialize() [function.unserialize]: Extra data starting at offset 3079 of 6170 bytes [CORE/cake/libs/cache/file.php, line 190]
Code
                $data = str_replace('\\\\\\\\', '\\', $data);
            }
            $data = unserialize((string)$data);
unserialize - [internal], line ??
FileEngine::read() - CORE/cake/libs/cache/file.php, line 190
Cache::read() - CORE/cake/libs/cache.php, line 362
DataSource::__cacheDescription() - CORE/cake/libs/model/datasources/datasource.php, line 475
DataSource::describe() - CORE/cake/libs/model/datasources/datasource.php, line 278
DboMysqlBase::describe() - CORE/cake/libs/model/datasources/dbo/dbo_mysql.php, line 120
Model::schema() - CORE/cake/libs/model/model.php, line 938
Model::setSource() - CORE/cake/libs/model/model.php, line 789
Model::__construct() - CORE/cake/libs/model/model.php, line 483
ClassRegistry::init() - CORE/cake/libs/class_registry.php, line 142
Model::__constructLinkedModel() - CORE/cake/libs/model/model.php, line 667
Model::__createLinks() - CORE/cake/libs/model/model.php, line 638
Model::__construct() - CORE/cake/libs/model/model.php, line 491
ClassRegistry::init() - CORE/cake/libs/class_registry.php, line 142
Controller::loadModel() - CORE/cake/libs/controller/controller.php, line 634
Controller::constructClasses() - CORE/cake/libs/controller/controller.php, line 501
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 186
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171

Warning (2): ini_set() [function.ini-set]: Session ini settings cannot be changed after headers have already been sent [CORE/cake/libs/cake_session.php, line 490]
Code
        }
        if ($iniSet && ($this->security === 'high' || $this->security === 'medium')) {
            ini_set('session.referer_check', $this->host);
ini_set - [internal], line ??
CakeSession::__initSession() - CORE/cake/libs/cake_session.php, line 490
CakeSession::start() - CORE/cake/libs/cake_session.php, line 230
SessionComponent::__start() - CORE/cake/libs/controller/components/session.php, line 287
SessionComponent::startup() - CORE/cake/libs/controller/components/session.php, line 74
Component::triggerCallback() - CORE/cake/libs/controller/component.php, line 186
Controller::startupProcess() - CORE/cake/libs/controller/controller.php, line 522
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 187
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171
[main] - APP/webroot/index.php, line 83

Warning (2): ini_set() [function.ini-set]: Session ini settings cannot be changed after headers have already been sent [CORE/cake/libs/cake_session.php, line 513]
Code
                }
            } else {
                ini_set('session.cookie_samesite', $this->cookieSameSite);
ini_set - [internal], line ??
CakeSession::__initSession() - CORE/cake/libs/cake_session.php, line 513
CakeSession::start() - CORE/cake/libs/cake_session.php, line 230
SessionComponent::__start() - CORE/cake/libs/controller/components/session.php, line 287
SessionComponent::startup() - CORE/cake/libs/controller/components/session.php, line 74
Component::triggerCallback() - CORE/cake/libs/controller/component.php, line 186
Controller::startupProcess() - CORE/cake/libs/controller/controller.php, line 522
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 187
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171
[main] - APP/webroot/index.php, line 83

Warning (2): ini_set() [function.ini-set]: Session ini settings cannot be changed after headers have already been sent [CORE/cake/libs/cake_session.php, line 565]
Code
                if (empty($_SESSION)) {
                    if ($iniSet) {
                        ini_set('session.use_trans_sid', 0);
ini_set - [internal], line ??
CakeSession::__initSession() - CORE/cake/libs/cake_session.php, line 565
CakeSession::start() - CORE/cake/libs/cake_session.php, line 230
SessionComponent::__start() - CORE/cake/libs/controller/components/session.php, line 287
SessionComponent::startup() - CORE/cake/libs/controller/components/session.php, line 74
Component::triggerCallback() - CORE/cake/libs/controller/component.php, line 186
Controller::startupProcess() - CORE/cake/libs/controller/controller.php, line 522
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 187
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171
[main] - APP/webroot/index.php, line 83

Warning (2): ini_set() [function.ini-set]: Session ini settings cannot be changed after headers have already been sent [CORE/cake/libs/cake_session.php, line 566]
Code
                    if ($iniSet) {
                        ini_set('session.use_trans_sid', 0);
                        ini_set('session.name', Configure::read('Session.cookie'));
ini_set - [internal], line ??
CakeSession::__initSession() - CORE/cake/libs/cake_session.php, line 566
CakeSession::start() - CORE/cake/libs/cake_session.php, line 230
SessionComponent::__start() - CORE/cake/libs/controller/components/session.php, line 287
SessionComponent::startup() - CORE/cake/libs/controller/components/session.php, line 74
Component::triggerCallback() - CORE/cake/libs/controller/component.php, line 186
Controller::startupProcess() - CORE/cake/libs/controller/controller.php, line 522
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 187
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171
[main] - APP/webroot/index.php, line 83

Warning (2): ini_set() [function.ini-set]: Session ini settings cannot be changed after headers have already been sent [CORE/cake/libs/cake_session.php, line 567]
Code
                        ini_set('session.use_trans_sid', 0);
                        ini_set('session.name', Configure::read('Session.cookie'));
                        ini_set('session.cookie_lifetime', $this->cookieLifeTime);
ini_set - [internal], line ??
CakeSession::__initSession() - CORE/cake/libs/cake_session.php, line 567
CakeSession::start() - CORE/cake/libs/cake_session.php, line 230
SessionComponent::__start() - CORE/cake/libs/controller/components/session.php, line 287
SessionComponent::startup() - CORE/cake/libs/controller/components/session.php, line 74
Component::triggerCallback() - CORE/cake/libs/controller/component.php, line 186
Controller::startupProcess() - CORE/cake/libs/controller/controller.php, line 522
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 187
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171
[main] - APP/webroot/index.php, line 83

Warning (2): ini_set() [function.ini-set]: Session ini settings cannot be changed after headers have already been sent [CORE/cake/libs/cake_session.php, line 568]
Code
                        ini_set('session.name', Configure::read('Session.cookie'));
                        ini_set('session.cookie_lifetime', $this->cookieLifeTime);
                        ini_set('session.cookie_path', $this->path);
ini_set - [internal], line ??
CakeSession::__initSession() - CORE/cake/libs/cake_session.php, line 568
CakeSession::start() - CORE/cake/libs/cake_session.php, line 230
SessionComponent::__start() - CORE/cake/libs/controller/components/session.php, line 287
SessionComponent::startup() - CORE/cake/libs/controller/components/session.php, line 74
Component::triggerCallback() - CORE/cake/libs/controller/component.php, line 186
Controller::startupProcess() - CORE/cake/libs/controller/controller.php, line 522
Dispatcher::_invoke() - CORE/cake/dispatcher.php, line 187
Dispatcher::dispatch() - CORE/cake/dispatcher.php, line 171
[main] - APP/webroot/index.php, line 83

Mayr's Database Of Reactivity Parameters

AK Prof. Mayr

• Start page

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Alkylating Boron Compounds

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Alkyl, Alkenyl and Aryl Boron Compounds

Found 10 Molecules.

Molecule	Solvent	Reactivity Parameters	Classification	Reference (sort by title or year)
lithium 2-benzyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 8.92 sN Parameter: 0.70		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 4,4,5,5-tetramethyl-2-phenyl-2-(1-phenylethyl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 10.97 sN Parameter: 0.63		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 2-benzyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 7.15 sN Parameter: 0.77		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 4,4,5,5-tetramethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 8.56 sN Parameter: 0.76		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-2-(1-phenylethyl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 7.46 sN Parameter: 0.76		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 2-benzyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 6.30 sN Parameter: 0.78		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 2-isopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 6.63 sN Parameter: 0.75		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 2-cyclopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 7.72 sN Parameter: 0.75		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 2-ethyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N  Parameter: 7.68 sN Parameter: 0.78		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918
lithium 5,5-dimethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborinan-2-uide (in MeCN)	MeCN	N  Parameter: 11.29 sN Parameter: 0.76		Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918

 

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