C=C-OSi
For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Enol Ethers
Found 35 Molecules.
| Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
|---|---|---|---|---|
 1,1-bis(trimethylsiloxy)propene | dichloromethane | N Parameter: 10.38 sN Parameter: 0.87 |  | Eur. J. Org. Chem. 2004, , 2791-2796 DOI: 10.1002/ejoc.200400134 |
 Danishefskys diene | dichloromethane | N Parameter: 8.57 sN Parameter: 0.84 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 3-(trimethylsiloxy)-1H-indene (in MeCN) | MeCN | N Parameter: 7.32 sN Parameter: 0.82 | | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 |
 2-(trimethylsiloxy)furan | dichloromethane | N Parameter: 7.22 sN Parameter: 1.00 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 1-(trimethylsiloxy)cyclooctene | dichloromethane | N Parameter: 6.77 sN Parameter: 1.00 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 1-(trimethylsiloxy)cycloheptene | dichloromethane | N Parameter: 6.62 sN Parameter: 1.00 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 1-(trimethylsiloxy)cyclopentene | dichloromethane | N Parameter: 6.57 sN Parameter: 0.93 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 1-(trimethylsiloxy)cyclopentene (in MeCN) | MeCN | N Parameter: 6.43 sN Parameter: 0.89 | | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 |
 1-phenyl-1-(trimethylsiloxy)ethene | dichloromethane | N Parameter: 6.22 sN Parameter: 0.96 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 2-(tris(trimethylsilyl)siloxy)propene | dichloromethane | N Parameter: 6.04 sN Parameter: 0.82 | | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e |
 1-(triphenylsiloxy)cyclopentene | dichloromethane | N Parameter: 5.76 sN Parameter: 1.02 | | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 |
 Z-3-(trimethylsiloxy)pent-2-ene | dichloromethane | N Parameter: 5.58 sN Parameter: 1.00 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 2-(tert.butyldimethylsiloxy)propene | dichloromethane | N Parameter: 5.58 sN Parameter: 0.90 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 2-(trimethylsiloxy)propene | dichloromethane | N Parameter: 5.41 sN Parameter: 0.91 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 3-methyl-2-(trimethylsiloxy)but-1-ene | dichloromethane | N Parameter: 5.41 sN Parameter: 0.90 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 2-(triisopropylsiloxy)propene | dichloromethane | N Parameter: 5.38 sN Parameter: 0.85 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 1-(trimethylsiloxy)cyclohexene | dichloromethane | N Parameter: 5.21 sN Parameter: 1.00 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 (Z)-1-phenyl-1-(trimethylsiloxy)propene (in MeCN) | MeCN | N Parameter: 5.18 sN Parameter: 0.94 | | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 |
 1-(tris(trimethylsilyl)siloxy)cyclohexene | dichloromethane | N Parameter: 5.07 sN Parameter: 0.91 | | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e |
 1-(trimethylsiloxy)-3,4-dihydronaphthalene (in MeCN) | MeCN | N Parameter: 5.06 sN Parameter: 0.91 | | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 |
 2-(trimethylsiloxy)buta-1,3-diene | dichloromethane | N Parameter: 4.83 sN Parameter: 0.90 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 1-(trimethylsiloxy)buta-1,3-diene | dichloromethane | N Parameter: 4.60 sN Parameter: 0.90 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 1,2-bis(trimethylsiloxy)cyclohexene | dichloromethane | N Parameter: 4.46 sN Parameter: 1.15 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 2-(triphenylsiloxy)propene | dichloromethane | N Parameter: 4.46 sN Parameter: 0.90 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 (tris(trimethylsilyl)siloxy)ethene | dichloromethane | N Parameter: 4.01 sN Parameter: 0.83 | | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e |
 2-methyl-1-(trimethylsiloxy)propen | dichloromethane | N Parameter: 3.94 sN Parameter: 1.00 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 (Z)-1-(triisopropylsiloxy)propen | dichloromethane | N Parameter: 3.87 sN Parameter: 1.00 | | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c |
 3,3-dimethyl-2-(trimethylsiloxy)buten | dichloromethane | N Parameter: 3.78 sN Parameter: 0.79 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 (triisopropylsiloxy)ethene | dichloromethane | N Parameter: 3.44 sN Parameter: 0.94 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y |
 (Z)-1,2-diphenyl-1-(trimethylsiloxy)ethene (in MeCN) | MeCN | N Parameter: 3.00 sN Parameter: 0.83 | | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 |
 1-(perfluorophenyl)-1-(trimethylsiloxy)ethene | dichloromethane | N Parameter: 1.47 sN Parameter: 0.89 | | Org. Lett. 2012, 14, 3990-3993 DOI: 10.1021/ol301766w |
 1-(tris(pentafluorophenyl)siloxy)-cyclopentene | dichloromethane | N Parameter: 1.38 sN Parameter: 0.93 | | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 |
 2-(tris(pentafluorophenyl)siloxy)-propene | dichloromethane | N Parameter: 0.58 sN Parameter: 0.91 | | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 |
 3,3,3-trifluoro-2-(trimethylsiloxy)propene | dichloromethane | N Parameter: -2.94 sN Parameter: 1.11 | | Org. Lett. 2012, 14, 3990-3993 DOI: 10.1021/ol301766w |
 (3,3,4,4,5,5,6,6,7,7,7-undecafluoro)-2-(trimethylsiloxy)hept-1-ene | dichloromethane | N Parameter: -3.52 sN Parameter: 1.17 | | Org. Lett. 2012, 14, 3990-3993 DOI: 10.1021/ol301766w |