Electrophiles
Found 367 Molecules.
Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
---|---|---|---|---|
benzhydrylium ion Ph2CH+ | 0 | E Parameter: 5.47 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(pcp)2CH+ | 0 | E Parameter: 5.48 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
pfp(Ph)CH+ | 0 | E Parameter: 5.20 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(fur)2CH+ | 0 | E Parameter: -1.36 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(ani)2CH+ | 0 | E Parameter: 0.00 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(tol)2CH+ | 0 | E Parameter: 3.63 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(pfa)2CH+ | 0 | E Parameter: -3.14 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(mfa)2CH+ | 0 | E Parameter: -3.85 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(dpa)2CH+ | 0 | E Parameter: -4.72 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(mor)2CH+ | 0 | E Parameter: -5.53 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(mpa)2CH+ | 0 | E Parameter: -5.89 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(dma)2CH+ | 0 | E Parameter: -7.02 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(pyr)2CH+ | 0 | E Parameter: -7.69 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(thq)2CH+ | 0 | E Parameter: -8.22 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(ind)2CH+ | 0 | E Parameter: -8.76 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(jul)2CH+ | 0 | E Parameter: -9.45 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(lil)2CH+ | 0 | E Parameter: -10.04 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
ani(pop)CH+ | 0 | E Parameter: 0.61 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
ani(Ph)CH+ | 0 | E Parameter: 2.11 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
ani(tol)CH+ | 0 | E Parameter: 1.48 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
pop(Ph)CH+ | 0 | E Parameter: 2.90 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
tol(Ph)CH+ | 0 | E Parameter: 4.43 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(pfp)2CH+ | 0 | E Parameter: 5.01 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
fc(Ph)CH+ | 0 | E Parameter: -2.64 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(fur)(ani)CH+ | 0 | E Parameter: -0.81 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(mfp)PhCH+ | 0 | E Parameter: 6.23 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(tfm)PhCH+ | 0 | E Parameter: 6.70 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(dfp)PhCH+ | 0 | E Parameter: 6.74 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(mfp)2CH+ | 0 | E Parameter: 6.87 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(dfp)(mfp)CH+ | 0 | E Parameter: 7.52 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(Ftol)2CH+ | 0 | E Parameter: 5.24 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
ani(Br)2QM | 0 | E Parameter: -8.63 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
ani(Ph)2QM | 0 | E Parameter: -12.18 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
dma(Ph)2QM | 0 | E Parameter: -13.39 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
tol(t-Bu)2QM | 0 | E Parameter: -15.83 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
ani(t-Bu)2QM | E Parameter: -16.11 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | ||
dma(t-Bu)2QM | E Parameter: -17.29 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | ||
jul(t-Bu)2QM | 0 | E Parameter: -17.90 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
5-methoxyfuroxano[3,4-d]pyrimidine | 0 | E Parameter: -8.37 | J. Phys. Org. Chem. 2003, 16, 431-437 DOI: 10.1002/poc.606 | |
benzylidenemalononitrile | 0 | E Parameter: -9.42 | J. Org. Chem. 2003, 68, 6880-6886 DOI: 10.1021/jo0344182 | |
p-(methoxy)benzylidenemalononitrile | 0 | E Parameter: -10.80 | J. Org. Chem. 2003, 68, 6880-6886 DOI: 10.1021/jo0344182 | |
p-(dimethylamino)benzylidenemalononitrile | 0 | E Parameter: -13.30 | J. Org. Chem. 2003, 68, 6880-6886 DOI: 10.1021/jo0344182 | |
pop(tol)CH+ | 0 | E Parameter: 2.16 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
fc(ani)CH+ | 0 | E Parameter: -2.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
fc2CH+ | 0 | E Parameter: -8.54 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
C7H7+-Fe(CO)3 | E Parameter: -3.49 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
C7H9+-Fe(CO)3 | E Parameter: -9.21 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
C6H7+-Fe(CO)3 | E Parameter: -7.76 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
C6H6OMe+-Fe(CO)3 | E Parameter: -8.94 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
benzaldehyde-boron trichloride complex | E Parameter: 1.12 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
4-chlorobenzaldehyde-boron trichloride complex | E Parameter: 1.44 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
tropylium ion | 0 | E Parameter: -3.72 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
propyn-1-ylium-Co2(CO)6 | E Parameter: -0.84 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
1-phenyl-proyn-ylium-Co2(CO)6 | E Parameter: -0.97 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
3-phenylpropyn-1-ylium-Co2(CO)6 | E Parameter: -1.58 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6 | E Parameter: -1.60 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3) | E Parameter: -6.19 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
2-phenyl-1,3-dithiolan-2-ylium ion | 0 | E Parameter: -5.91 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-phenyl-1,3-dithianylium ion | 0 | E Parameter: -6.43 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1,3-dithianylium ion | 0 | E Parameter: -2.14 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
N-ethylidenecarbazolium ion | 0 | E Parameter: 2.41 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
N-methylacridinium ion | 0 | E Parameter: -7.15 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methoxy-phenylmethylium ion | 0 | E Parameter: 2.97 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methoxy-(4-methoxyphenyl)methylium ion | 0 | E Parameter: 0.14 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methoxy-(4-methylphenyl)methylium ion | 0 | E Parameter: 1.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
Pd-allyl cation | E Parameter: -10.11 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
flavylium ion | 0 | E Parameter: -3.45 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(4-methoxyphenyl)chromenylium ion | 0 | E Parameter: -4.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1,1,3-triphenylallylium ion | 0 | E Parameter: 0.98 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1,1-dianisyl-3-phenylallylium ion | 0 | E Parameter: -2.67 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1,1-bis(4-dimethylaminophenyl)-3-phenylallylium ion | 0 | E Parameter: -8.97 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1,1,3-tris(4-(dimethylamino)phenyl)allylium ion | 0 | E Parameter: -9.84 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1-phenylcyclopent-2-enylium ion | 0 | E Parameter: 2.89 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1-(4-chlorophenyl)cyclopent-2-enylium ion | 0 | E Parameter: 3.20 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1,3-diphenylpropyn-1-ylium-Cr(CO)3 | E Parameter: 1.07 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
1,1,3-triphenylpropyn-1-ylium-Cr(CO)3 | E Parameter: -0.25 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | ||
4,6-dinitrobenzofuroxan | 0 | E Parameter: -5.06 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
1,3,5-trinitrobenzene | 0 | E Parameter: -13.19 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
6-nitro-tetrazolo[1,5a]pyridine | 0 | E Parameter: -9.05 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
dicarbonyl(cyclopentadienyl)propene-iron(II) | E Parameter: -11.20 | Helv. Chim. Acta 2005, 88, 1754-1768 DOI: 10.1002/hlca.200590137 | ||
4-nitro-6-(trifluoromethylsulfonyl)benzofuroxan | 0 | E Parameter: -4.91 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
4,6-dinitrotetrazolopyridine | 0 | E Parameter: -4.67 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
4,6-dinitrobenzofurazan | 0 | E Parameter: -5.46 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
2,4-dinitrothiophene | 0 | E Parameter: -12.33 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
6-cyano-4-nitrobenzofuroxan | 0 | E Parameter: -7.01 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
4-cyano-6-nitro-benzofuroxane | 0 | E Parameter: -6.41 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
4-aza-6-nitrobenzofuroxan | 0 | E Parameter: -5.86 | J. Org. Chem. 2005, 70, 6242-6253 DOI: 10.1021/jo0505526 | |
2-(p-(dimethylamino)benzylidene)-indan-1,3-dione | 0 | E Parameter: -13.56 | Org. Biomol. Chem. 2007, 5, 3020-3026 DOI: 10.1039/b708025e | |
2-(p-methoxybenzylidene)-indan-1,3-dione | 0 | E Parameter: -11.32 | Org. Biomol. Chem. 2007, 5, 3020-3026 DOI: 10.1039/b708025e | |
2-benzylidene-indan-1,3-dione | 0 | E Parameter: -10.11 | Org. Biomol. Chem. 2007, 5, 3020-3026 DOI: 10.1039/b708025e | |
jul-indan-1,3-dione | 0 | E Parameter: -14.68 | Org. Biomol. Chem. 2007, 5, 3020-3026 DOI: 10.1039/b708025e | |
aniBBS | 0 | E Parameter: -10.37 | J. Org. Chem. 2007, 72, 9170-9180 DOI: 10.1021/jo071273g | |
dmaBBS | 0 | E Parameter: -12.76 | J. Org. Chem. 2007, 72, 9170-9180 DOI: 10.1021/jo071273g | |
julBBS | 0 | E Parameter: -13.84 | J. Org. Chem. 2007, 72, 9170-9180 DOI: 10.1021/jo071273g | |
dma(S)BBS | 0 | E Parameter: -10.73 | J. Org. Chem. 2007, 72, 9170-9180 DOI: 10.1021/jo071273g | |
jul(S)BBS | 0 | E Parameter: -11.89 | J. Org. Chem. 2007, 72, 9170-9180 DOI: 10.1021/jo071273g | |
4-nitrobenzodifuroxan (NBDF) | 0 | E Parameter: -6.15 | Chem. Eur. J. 2007, 13, 8317-8324 DOI: 10.1002/chem.200700676 | |
benzylidene-Meldrum's acid | 0 | E Parameter: -9.15 | J. Org. Chem. 2008, 73, 2738-2745 DOI: 10.1021/jo702590s | |
p-(methoxy)benzylidene Meldrum's acid | 0 | E Parameter: -10.28 | J. Org. Chem. 2008, 73, 2738-2745 DOI: 10.1021/jo702590s | |
p-(dimethylamino)benzylidene Meldrum's acid | 0 | E Parameter: -12.76 | J. Org. Chem. 2008, 73, 2738-2745 DOI: 10.1021/jo702590s | |
jul Meldrum's acid | 0 | E Parameter: -13.97 | J. Org. Chem. 2008, 73, 2738-2745 DOI: 10.1021/jo702590s | |
diethyl benzylidene malonate | 0 | E Parameter: -20.55 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
diethyl 4-nitrobenzylidene malonate | 0 | E Parameter: -17.67 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
diethyl 4-cyano-benzylidene malonate | 0 | E Parameter: -18.06 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
diethyl 3-chloro-benzylidene malonate | 0 | E Parameter: -18.98 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
diethyl 4-methyl-benzylidene malonate | 0 | E Parameter: -21.11 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
diethyl 4-methoxy-benzylidene malonate | 0 | E Parameter: -21.47 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
diethyl 4-(dimethylamino)benzylidene malonate | 0 | E Parameter: -23.10 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
Me2N+=CH-CH-Ph | 0 | E Parameter: -9.20 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 DOI: 10.1002/anie.200802889 | |
pyrN+=CH-CH-Ph | 0 | E Parameter: -9.80 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 DOI: 10.1002/anie.200802889 | |
(PhCH2)2N+=CH-CH-Ph | 0 | E Parameter: -8.50 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 DOI: 10.1002/anie.200802889 | |
Jorgensen/Hayashi-iminium ion | 0 | E Parameter: -8.20 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 DOI: 10.1002/anie.200802889 | |
MacMillan-iminium ion (1st generation) | MeCN | E Parameter: -7.37 | Angew. Chem. Int. Ed. 2011, 50, 9953-9956 DOI: 10.1002/anie.201103683 | |
mor iminium | 0 | E Parameter: -8.60 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 DOI: 10.1002/anie.200802889 | |
2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone | 0 | E Parameter: -11.87 | Eur. J. Org. Chem. 2009, , 3203-3211 DOI: 10.1002/ejoc.200900299 | |
2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone | 0 | E Parameter: -16.38 | Eur. J. Org. Chem. 2009, , 3203-3211 DOI: 10.1002/ejoc.200900299 | |
2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone | 0 | E Parameter: -17.18 | Eur. J. Org. Chem. 2009, , 3203-3211 DOI: 10.1002/ejoc.200900299 | |
2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone | 0 | E Parameter: -16.36 | Eur. J. Org. Chem. 2009, , 3203-3211 DOI: 10.1002/ejoc.200900299 | |
2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone | 0 | E Parameter: -15.03 | Eur. J. Org. Chem. 2009, , 3203-3211 DOI: 10.1002/ejoc.200900299 | |
2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone | 0 | E Parameter: -14.50 | Eur. J. Org. Chem. 2009, , 3203-3211 DOI: 10.1002/ejoc.200900299 | |
2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone | 0 | E Parameter: -14.36 | Eur. J. Org. Chem. 2009, , 3203-3211 DOI: 10.1002/ejoc.200900299 | |
cumyl cation | E Parameter: 5.74 | Macromolecules 2010, 43, 1719-1723 DOI: 10.1021/ma9024569 | ||
1,2-diaza-1,3-diene 1a | DMSO | E Parameter: -13.28 | Chem. Eur. J. 2010, 16, 12008-12016 DOI: 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1b | DMSO | E Parameter: -13.90 | Chem. Eur. J. 2010, 16, 12008-12016 DOI: 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1c | DMSO | E Parameter: -14.91 | Chem. Eur. J. 2010, 16, 12008-12016 DOI: 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1d | DMSO | E Parameter: -15.38 | Chem. Eur. J. 2010, 16, 12008-12016 DOI: 10.1002/chem.201000828 | |
2,3,4,5,6,6-hexachlorocyclohexa-2,4-dien-1-one | MeCN | E Parameter: -6.75 | Org. Lett. 2010, 12, 2238-2241 DOI: 10.1021/ol100592j | |
5,7,7-trichloro-8(7H)-quinolinone | MeCN | E Parameter: -10.48 | Org. Lett. 2010, 12, 2238-2241 DOI: 10.1021/ol100592j | |
2,2,4-trichloro-1(2H)-naphthalenone | MeCN | E Parameter: -11.24 | Org. Lett. 2010, 12, 2238-2241 DOI: 10.1021/ol100592j | |
dibenzyl azodicarboxylate | MeCN | E Parameter: -8.89 | Chem. Eur. J. 2010, 16, 11670-11677 DOI: 10.1002/chem.201001598 | |
diethyl azodicarboxylate | MeCN | E Parameter: -10.15 | Chem. Eur. J. 2010, 16, 11670-11677 DOI: 10.1002/chem.201001598 | |
diisopropyl azodicarboxylate | MeCN | E Parameter: -10.71 | Chem. Eur. J. 2010, 16, 11670-11677 DOI: 10.1002/chem.201001598 | |
di-tert-butyl azodicarboxylate | MeCN | E Parameter: -12.23 | Chem. Eur. J. 2010, 16, 11670-11677 DOI: 10.1002/chem.201001598 | |
(E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) | DMSO | E Parameter: -17.33 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
(E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) | DMSO | E Parameter: -17.64 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
(E)-1,3-diphenylprop-2-en-1-one (in DMSO) | DMSO | E Parameter: -19.39 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
(E)-N-benzylidene-4-methylbenzenesulfonamide (in DMSO) | DMSO | E Parameter: -11.50 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
(E)-N-(4-methoxybenzylidene)-4-methylbenzenesulfonamide (in DMSO) | DMSO | E Parameter: -13.05 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
(E)-N-(4-(dimethylamino)benzylidene)-4-methylbenzenesulfonamide (in DMSO) | DMSO | E Parameter: -15.09 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
(E)-tert-butyl benzylidenecarbamate (in DMSO) | DMSO | E Parameter: -14.22 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
(E)-N-benzylidene-P,P-diphenylphosphinic amide | DMSO | E Parameter: -15.89 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
diarylallylium ion (3,3-F2)2 | E Parameter: 6.11 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
diarylallylium ion (4-Br)2 | E Parameter: 2.85 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
diphenylallylium ion | E Parameter: 2.70 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
di-p-tolyl-allylium ion | E Parameter: 1.23 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
di-p-anisyl-allylium ion | E Parameter: -1.45 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
diarylallylium ion (4-NMe2)2 | E Parameter: -7.50 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
bis(julidin-9-yl)allylium ion | E Parameter: -9.78 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
4-methoxy-<i>trans-beta</i>-nitrostyrene | E Parameter: -14.70 | J. Org. Chem. 2011, 76, 9370-9378 DOI: 10.1021/jo201678u | ||
4-methyl-<i>trans-beta</i>-nitrostyrene | E Parameter: -14.23 | J. Org. Chem. 2011, 76, 9370-9378 DOI: 10.1021/jo201678u | ||
<i>trans-beta</i>-nitrostyrene | E Parameter: -13.85 | J. Org. Chem. 2011, 76, 9370-9378 DOI: 10.1021/jo201678u | ||
4-bromo-<i>trans-beta</i>-nitrostyrene | E Parameter: -13.37 | J. Org. Chem. 2011, 76, 9370-9378 DOI: 10.1021/jo201678u | ||
4-cyano-<i>trans-beta</i>-nitrostyrene | E Parameter: -12.61 | J. Org. Chem. 2011, 76, 9370-9378 DOI: 10.1021/jo201678u | ||
4-nitro-<i>trans-beta</i>-nitrostyrene | E Parameter: -12.37 | J. Org. Chem. 2011, 76, 9370-9378 DOI: 10.1021/jo201678u | ||
(ethene-1,1-diyldisulfonyl)dibenzene | DMSO | E Parameter: -7.50 | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 | |
(2-phenylethene-1,1-diyldisulfonyl)dibenzene | DMSO | E Parameter: -12.93 | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 | |
(2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene | DMSO | E Parameter: -13.88 | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 | |
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline | DMSO | E Parameter: -16.53 | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 | |
2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide | DMSO | E Parameter: -11.78 | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 | |
2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide | DMSO | E Parameter: -13.02 | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 | |
2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide | DMSO | E Parameter: -14.55 | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 | |
MacMillan-iminium ion (2nd generation) | MeCN | E Parameter: -5.52 | Angew. Chem. Int. Ed. 2011, 50, 9953-9956 DOI: 10.1002/anie.201103683 | |
MacMillan-iminium ion (spiro) | MeCN | E Parameter: -7.67 | Angew. Chem. Int. Ed. 2011, 50, 9953-9956 DOI: 10.1002/anie.201103683 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph) | E Parameter: -14.14 | Organometallics 2012, 31, 2416-2424 DOI: 10.1021/om3000357 | ||
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl) | E Parameter: -14.21 | Organometallics 2012, 31, 2416-2424 DOI: 10.1021/om3000357 | ||
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl) | E Parameter: -14.46 | Organometallics 2012, 31, 2416-2424 DOI: 10.1021/om3000357 | ||
2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium | DMSO | E Parameter: -11.52 | Angew. Chem. Int. Ed. 2012, 51, 5234-5238 DOI: 10.1002/anie.201109042 | |
PhCH=N+Me2 (in MeCN) | MeCN | E Parameter: -9.27 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
pTolCH=N+CH2 (in MeCN) | MeCN | E Parameter: -9.64 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
p-AniCH=N+Me2 (in MeCN) | MeCN | E Parameter: -10.69 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
PhCH=N+(CH2)4 (in MeCN) | MeCN | E Parameter: -9.35 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
PhCH=N+(CH2)5 (in MeCN) | MeCN | E Parameter: -9.60 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
p-CF3-C6H4-CH=N+Me2 (in MeCN) | MeCN | E Parameter: -8.34 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) | MeCN | E Parameter: -3.66 | J. Am. Chem. Soc. 2013, 135, 12377-12387 DOI: 10.1021/ja405890d | |
maleic anhydride | DMSO | E Parameter: -11.31 | Eur. J. Org. Chem. 2014, , 2956-2963 DOI: 10.1002/ejoc.201301779 | |
N-methyl maleimide | DMSO | E Parameter: -14.07 | Eur. J. Org. Chem. 2014, , 2956-2963 DOI: 10.1002/ejoc.201301779 | |
fumaronitrile | DMSO | E Parameter: -15.71 | Eur. J. Org. Chem. 2014, , 2956-2963 DOI: 10.1002/ejoc.201301779 | |
diethyl fumarate | DMSO | E Parameter: -17.79 | Eur. J. Org. Chem. 2014, , 2956-2963 DOI: 10.1002/ejoc.201301779 | |
diethyl maleate | DMSO | E Parameter: -19.49 | Eur. J. Org. Chem. 2014, , 2956-2963 DOI: 10.1002/ejoc.201301779 | |
2,5-dichloroquinone (C-H) | 0 | E Parameter: -12.28 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
2,5-dichloroquinone (C-Cl) | 0 | E Parameter: -16.11 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
p-chloranil (C=O) | 0 | E Parameter: -12.13 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
p-chloranil (C-Cl) | 0 | E Parameter: -13.84 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
p-fluoranil (C=O) | 0 | E Parameter: -9.37 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
p-fluoranil (C-F) | 0 | E Parameter: -11.12 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
o-chloranil (C=O) | 0 | E Parameter: -8.77 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
o-chloranil (C-Cl) | 0 | E Parameter: -12.02 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
3-benzylidene-1-methyl-3H-indol-1-ium ion | 0 | E Parameter: -1.80 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion | 0 | E Parameter: -2.19 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom | 0 | E Parameter: -3.02 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion | 0 | E Parameter: -6.26 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
1-methyl-3-((julolidin-9-yl)methylene)-3H-indol-1-ium ion | 0 | E Parameter: -7.79 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
(E)-2-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion | 0 | E Parameter: -5.15 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
(E)-1,2-dimethyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion | 0 | E Parameter: -5.05 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
bis(1-methylindol-3-yl)methylium ion | 0 | E Parameter: -5.99 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
bis(5-methoxy-1-methylindol-3-yl)methylium ion | 0 | E Parameter: -6.90 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
bis(1,2-dimethylindol-3-yl)methylium ion | 0 | E Parameter: -10.23 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
ethenesulfonyl fluoride (ESF) | DMSO | E Parameter: -12.09 | Angew. Chem. Int. Ed. 2016, 55, 12664-12667 DOI: 10.1002/anie.201601875 | |
2-phenylethene-1-sulfonyl fluoride | DMSO | E Parameter: -16.63 | Angew. Chem. Int. Ed. 2016, 55, 12664-12667 DOI: 10.1002/anie.201601875 | |
9-phenyl-9H-fluoren-9-ylium | dichloromethane | E Parameter: 2.41 | Chem. Eur. J. 2017, 23, 623-630 DOI: 10.1002/chem.201603963 | |
9-(4-methoxyphenyl)-9H-fluoren-9-ylium | dichloromethane | E Parameter: 0.85 | Chem. Eur. J. 2017, 23, 623-630 DOI: 10.1002/chem.201603963 | |
9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium | dichloromethane | E Parameter: -4.51 | Chem. Eur. J. 2017, 23, 623-630 DOI: 10.1002/chem.201603963 | |
(E)-4-phenylbut-3-en-2-one (in DMSO) | DMSO | E Parameter: -23.01 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
methyl prop-2-enoate (in DMSO) | DMSO | E Parameter: -18.84 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
ethyl prop-2-enoate (in DMSO) | DMSO | E Parameter: -19.07 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
tert-butyl prop-2-enoate (in DMSO) | DMSO | E Parameter: -20.22 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
N,N-dimethylprop-2-enamide (in DMSO) | DMSO | E Parameter: -23.54 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
ethenylsulfonylbenzene (in DMSO) | DMSO | E Parameter: -18.36 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
acrylonitrile (in DMSO) | DMSO | E Parameter: -19.05 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
but-3-en-2-one (in DMSO) | DMSO | E Parameter: -16.76 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
1-phenylprop-2-en-1-one (in DMSO) | DMSO | E Parameter: -15.25 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium | DMSO | E Parameter: -10.09 | Top. Catal. 2018, 61, 585-590 DOI: 10.1007/s11244-018-0914-5 | |
1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium | DMSO | E Parameter: -11.80 | Top. Catal. 2018, 61, 585-590 DOI: 10.1007/s11244-018-0914-5 | |
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium | DMSO | E Parameter: -11.48 | Top. Catal. 2018, 61, 585-590 DOI: 10.1007/s11244-018-0914-5 | |
2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium | DMSO | E Parameter: -11.79 | Top. Catal. 2018, 61, 585-590 DOI: 10.1007/s11244-018-0914-5 | |
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium | DMSO | E Parameter: -12.02 | Top. Catal. 2018, 61, 585-590 DOI: 10.1007/s11244-018-0914-5 | |
N-(phenylsulfonyl)-N-((trifluoromethyl)thio)benzenesulfonamide | 0 | E Parameter: -6.06 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate | 0 | E Parameter: -10.46 | J. Am. Chem. Soc. 2018, 140, 11474-11486 DOI: 10.1021/jacs.8b07147 | |
N-fluoro-2,6-dichloropyridinium tetrafluoroborate | 0 | E Parameter: -5.29 | J. Am. Chem. Soc. 2018, 140, 11474-11486 DOI: 10.1021/jacs.8b07147 | |
Selectfluor | 0 | E Parameter: -5.20 | J. Am. Chem. Soc. 2018, 140, 11474-11486 DOI: 10.1021/jacs.8b07147 | |
NFSI | MeCN | E Parameter: -8.44 | J. Am. Chem. Soc. 2018, 140, 11474-11486 DOI: 10.1021/jacs.8b07147 | |
N-fluoropyridinium tetrafluoroborate | 0 | E Parameter: -9.89 | J. Am. Chem. Soc. 2018, 140, 11474-11486 DOI: 10.1021/jacs.8b07147 | |
N-(trifluoromethyl)thio)phthalimide | 0 | E Parameter: -11.92 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
N-(trifluoromethyl)thio)saccharin | 0 | E Parameter: -6.48 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
N-(trifluoromethyl)thio)succinimide | 0 | E Parameter: -12.56 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
N-(difluoromethyl)thio)phthalimide | 0 | E Parameter: -11.86 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide | 0 | E Parameter: -13.44 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
((2-phenylpropan-2-yl)oxy)(trifluoromethyl)sulfane | 0 | E Parameter: -13.77 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane | 0 | E Parameter: -14.52 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
2-methylcyclopentenone | DMSO | E Parameter: -22.10 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
cyclopentenone | DMSO | E Parameter: -20.60 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
furan-2(5H)-one | DMSO | E Parameter: -20.70 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
cyclohexenone | DMSO | E Parameter: -22.10 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
3-methylenetetrahydropyran-2-one | DMSO | E Parameter: -19.50 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
3-methylenedihydrofuranone | DMSO | E Parameter: -19.40 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
(E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one | DMSO | E Parameter: -17.00 | Org. Lett. 2020, 22, 2182-2186 DOI: 10.1021/acs.orglett.0c00338 | |
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Parameter: -16.84 | Org. Lett. 2020, 22, 2182-2186 DOI: 10.1021/acs.orglett.0c00338 | |
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Parameter: -16.25 | Org. Lett. 2020, 22, 2182-2186 DOI: 10.1021/acs.orglett.0c00338 | |
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Parameter: -17.42 | Org. Lett. 2020, 22, 2182-2186 DOI: 10.1021/acs.orglett.0c00338 | |
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one | DMSO | E Parameter: -11.68 | Eur. J. Org. Chem. 2020, , 3812-3817 DOI: 10.1002/ejoc.202000295 | |
3-nitro-1-tosyl-1H-indole | 0 | E Parameter: -14.87 | Chem. Commun. 2021, 57, 10071-10074 DOI: 10.1039/d1cc04074j | |
phenyl isocyanate | MeCN | E Parameter: -15.38 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
p-tosyl isocyanate | MeCN | E Parameter: -7.69 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
phenyl isothiocyanate | DMSO | E Parameter: -18.15 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
p-nitrophenyl isothiocyanate | DMSO | E Parameter: -15.89 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
diphenylcarbodiimide | DMSO | E Parameter: -20.14 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
carbon disulfide | DMSO | E Parameter: -17.70 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
3,6-dinitro-1-tosyl-1H-indole | 0 | E Parameter: -12.90 | Chem. Commun. 2021, 57, 10071-10074 DOI: 10.1039/d1cc04074j | |
cycloheptenone | DMSO | E Parameter: -22.00 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
methyl diazoacetate | 0 | E Parameter: -18.50 | Chem. Eur. J. 2022, 28, e202201376 DOI: 10.1002/chem.202201376 | |
dimethyl diazomalonate | 0 | E Parameter: -18.20 | Chem. Eur. J. 2022, 28, e202201376 DOI: 10.1002/chem.202201376 | |
(p-nitrophenyl)diazomethane | 0 | E Parameter: -18.30 | Chem. Eur. J. 2022, 28, e202201376 DOI: 10.1002/chem.202201376 | |
Umemoto I (triflate) | 0 | E Parameter: -13.08 | Eur. J. Org. Chem. 2024, 27, e202400085 DOI: 10.1002/ejoc.202400085 | |
Umemoto I (tetrafluoroborate) | 0 | E Parameter: -13.39 | Eur. J. Org. Chem. 2024, 27, e202400085 DOI: 10.1002/ejoc.202400085 | |
Umemoto II (triflate) | 0 | E Parameter: -12.80 | Eur. J. Org. Chem. 2024, 27, e202400085 DOI: 10.1002/ejoc.202400085 | |
(E)-6-(4-nitrobenzylidene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -13.15 | Chem. Eur. J. 2024, , e202403785 DOI: 10.1002/chem.202403785 | |
(E)-6-(4-(trifluoromethyl)benzylidene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -13.54 | Chem. Eur. J. 2024, , e202403785 DOI: 10.1002/chem.202403785 | |
(E)-6-(3-fluorobenzylidene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -14.00 | Chem. Eur. J. 2024, , e202403785 DOI: 10.1002/chem.202403785 | |
(E)-6-(4-chlorobenzylidene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -13.99 | Chem. Eur. J. 2024, , e202403785 DOI: 10.1002/chem.202403785 | |
(E)-6-benzylidenebenzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -14.47 | Chem. Eur. J. 2024, , e202403785 DOI: 10.1002/chem.202403785 | |
(E)-6-(4-methylbenzylidene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -14.85 | Chem. Eur. J. 2024, , e202403785 DOI: 10.1002/chem.202403785 | |
(E)-6-(4-methoxybenzylidene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -15.20 | Chem. Eur. J. 2024, , e202403785 DOI: 10.1002/chem.202403785 | |
(E)-6-(4-(dimethylamino)benzylidene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -16.07 | Chem. Eur. J. 2024, , e202403785 DOI: 10.1002/chem.202403785 | |
(E)-6-(furan-2-ylmethylene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -15.73 | Org. Biomol. Chem. 2024, , accepted DOI: 10.1039/D4OB01855A | |
(E)-6-((1-methyl-1H-pyrrol-2-yl)methylene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -17.03 | Org. Biomol. Chem. 2024, , accepted DOI: 10.1039/D4OB01855A | |
(E)-6-((1-methyl-1H-indol-2-yl)methylene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -15.55 | Org. Biomol. Chem. 2024, , accepted DOI: 10.1039/D4OB01855A | |
(E)-6-((E)-3-phenylallylidene)benzo[d][1,3]dioxol-5(6H)-one | 0 | E Parameter: -16.00 | Org. Biomol. Chem. 2024, , accepted DOI: 10.1039/D4OB01855A | |
bh6a | E Parameter: -18.60 | Chem. Eur. J. 2010, 16, 1365-1371 DOI: 10.1002/chem.200902487 | ||
bh 6f | E Parameter: -18.90 | Chem. Eur. J. 2010, 16, 1365-1371 DOI: 10.1002/chem.200902487 | ||
bh 6i | E Parameter: -19.10 | Chem. Eur. J. 2010, 16, 1365-1371 DOI: 10.1002/chem.200902487 | ||
bh6j | E Parameter: -17.90 | Chem. Eur. J. 2010, 16, 1365-1371 DOI: 10.1002/chem.200902487 | ||
diarylallylium ion (3-F)2 | E Parameter: 4.15 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
indolecarboxylate derived iminium ion | dichloromethane | E Parameter: -9.50 | Angew. Chem. Int. Ed. 2009, 48, 5034-5037 DOI: 10.1002/anie.200900933 | |
(tfm)2CH+ | 0 | E Parameter: 7.96 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium | dichloromethane | E Parameter: -6.00 | Angew. Chem. Int. Ed. 2013, 52, 7967-7971 DOI: 10.1002/anie.201301864 | |
(S,E)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)-5-(3,4,5-trimethoxybenzyl)imidazolidin-1-ium | dichloromethane | E Parameter: -7.00 | Angew. Chem. Int. Ed. 2013, 52, 7967-7971 DOI: 10.1002/anie.201301864 | |
(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(4-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium | dichloromethane | E Parameter: -5.90 | Asian J. Org. Chem. 2014, 3, 550-555 DOI: 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-1-((E)-3-(4-cyanophenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium | dichloromethane | E Parameter: -6.00 | Asian J. Org. Chem. 2014, 3, 550-555 DOI: 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-1-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium | dichloromethane | E Parameter: -10.60 | Asian J. Org. Chem. 2014, 3, 550-555 DOI: 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-2,2,3-trimethyl-4-oxo-1-((E)-3-(p-tolyl)allylidene)imidazolidin-1-ium | dichloromethane | E Parameter: -7.20 | Asian J. Org. Chem. 2014, 3, 550-555 DOI: 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-1-((E)-3-(4-methoxyphenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium | dichloromethane | E Parameter: -8.00 | Asian J. Org. Chem. 2014, 3, 550-555 DOI: 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(3-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium | dichloromethane | E Parameter: -6.10 | Asian J. Org. Chem. 2014, 3, 550-555 DOI: 10.1002/ajoc.201402009 | |
(S,E)-5-((1H-indol-3-yl)methyl)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)imidazolidin-1-ium | dichloromethane | E Parameter: -7.30 | Asian J. Org. Chem. 2014, 3, 550-555 DOI: 10.1002/ajoc.201402009 | |
(2S,5S)-5-benzyl-3-methyl-4-oxo-1-(3-phenylallylidene)-2-((E)-styryl)imidazolidin-1-ium | dichloromethane | E Parameter: -5.90 | Asian J. Org. Chem. 2014, 3, 550-555 DOI: 10.1002/ajoc.201402009 | |
p-quinone (C-H) | 0 | E Parameter: -16.19 | J. Am. Chem. Soc. 2014, 136, 11499-11512 DOI: 10.1021/ja505613b | |
(E)-3-benzylidene-1,2-dimethyl-3H-indol-1-ium ion | 0 | E Parameter: -4.96 | J. Org. Chem. 2015, 80, 8643-8656 DOI: 10.1021/acs.joc.5b01298 | |
ethyl 2-methylprop-2-enoate (in DMSO) | DMSO | E Parameter: -22.77 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
ethyl (E)-but-2-enoate (in DMSO) | DMSO | E Parameter: -23.59 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
ethyl cinnamate (in DMSO) | DMSO | E Parameter: -24.52 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
(E)-1-methyl-4-(styrylsulfonyl)benzene (in DMSO) | DMSO | E Parameter: -24.69 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
dihydro-2H-pyran-2-one | DMSO | E Parameter: -21.80 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
ethyl 3-nitro-1H-indole-1-carboxylate | 0 | E Parameter: -14.10 | Chem. Commun. 2021, 57, 10071-10074 DOI: 10.1039/d1cc04074j | |
4-bromo-3-nitro-1-tosyl-1H-indole | 0 | E Parameter: -14.60 | Chem. Commun. 2021, 57, 10071-10074 DOI: 10.1039/d1cc04074j | |
fc(Me)CH+ | 0 | E Parameter: -2.57 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
dimethylmethyleneammonium ion | 0 | E Parameter: -6.69 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methyl(phenyl)methyleneammonium ion | 0 | E Parameter: -5.17 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
Vilsmeier ion | 0 | E Parameter: -5.77 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2,4,6-trimethylphenyl)ethylium ion | 0 | E Parameter: 6.04 | Macromolecules 2005, 38, 33-40 DOI: 10.1021/ma048389o | |
1,3-bis(2,4,6-trimethylphenyl)but-1-ylium ion | 0 | E Parameter: 6.16 | Macromolecules 2005, 38, 33-40 DOI: 10.1021/ma048389o | |
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate | 0 | E Parameter: -23.40 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
diethyl 2-((julolidine-9-yl)methylene)malonate | 0 | E Parameter: -23.80 | Chem. Eur. J. 2008, 14, 9675-9682 DOI: 10.1002/chem.200801277 | |
pipN+=CH-CH-Ph | 0 | E Parameter: -10.30 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 DOI: 10.1002/anie.200802889 | |
bh 6k | E Parameter: -18.20 | Chem. Eur. J. 2010, 16, 1365-1371 DOI: 10.1002/chem.200902487 | ||
bh 6l | E Parameter: -18.90 | Chem. Eur. J. 2010, 16, 1365-1371 DOI: 10.1002/chem.200902487 | ||
bh 6m | E Parameter: -17.30 | Chem. Eur. J. 2010, 16, 1365-1371 DOI: 10.1002/chem.200902487 | ||
1,2-diaza-1,3-diene 1e | MeOH | E Parameter: -14.90 | Chem. Eur. J. 2010, 16, 12008-12016 DOI: 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1f | MeOH | E Parameter: -15.30 | Chem. Eur. J. 2010, 16, 12008-12016 DOI: 10.1002/chem.201000828 | |
(E)-4-(4-nitrophenyl)but-3-en-2-one (in DSMO) | DMSO | E Parameter: -19.36 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
(E)-4-methyl-1-(4-nitrophenyl)pent-1-en-3-one (in DMSO) | DMSO | E Parameter: -19.17 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
(E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one | DMSO | E Parameter: -19.15 | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | |
benzaldehyde (in DMSO) | DMSO | E Parameter: -12.90 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
(4-F)-tritylium ion | E Parameter: 0.35 | Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 | ||
(4-F)2-tritylium ion | E Parameter: 0.17 | Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 | ||
(4-F)3-tritylium ion | E Parameter: 0.05 | Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 | ||
(3-F)-tritylium ion | E Parameter: 1.01 | Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 | ||
(3-F)2-tritylium ion | E Parameter: 1.54 | Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 | ||
(3-F)3-tritylium ion | E Parameter: 2.07 | Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 | ||
(3-F)4-tritylium ion | E Parameter: 2.54 | Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 | ||
diarylallylium ion (4-Cl)2 | E Parameter: 2.69 | J. Org. Chem. 2011, 76, 9391-9408 DOI: 10.1021/jo201668w | ||
(dfp)2CH+ | 0 | E Parameter: 8.02 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(E)-2-(tert-butyl)-3-(4-methylbenzylidene)-3H-indol-1-ium | dichloromethane | E Parameter: -5.06 | Eur. J. Org. Chem. 2016, , 4050-4058 DOI: 10.1002/ejoc.201600572 | |
cinnamonitrile (in DMSO) | DMSO | E Parameter: -24.60 | J. Am. Chem. Soc. 2017, 139, 13318-13329 DOI: 10.1021/jacs.7b05106 | |
cyclobutanone (in DMSO) | DMSO | E Parameter: -17.50 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
cyclopentanone (in DMSO) | DMSO | E Parameter: -21.00 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
cyclohexanone (in DMSO) | DMSO | E Parameter: -19.90 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
cycloheptanone (in DMSO) | DMSO | E Parameter: -22.10 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
1-methylpiperidin-4-one (in DMSO) | DMSO | E Parameter: -18.40 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
oxan-4-one (in DMSO) | DMSO | E Parameter: -17.90 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
thian-4-one (in DMSO) | DMSO | E Parameter: -16.90 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
1,4-dioxaspiro[4.5]decan-8-one (in DMSO) | DMSO | E Parameter: -18.20 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
pentan-2-one (in DMSO) | DMSO | E Parameter: -22.30 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
1-methylsulfanylpropan-2-one (in DMSO) | DMSO | E Parameter: -15.60 | J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 | |
N-methyl-N-((trifluoromethyl)thio)-aniline | 0 | E Parameter: -23.32 | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 DOI: 10.1002/anie.201805859 | |
3-methylcyclopentenone | DMSO | E Parameter: -28.90 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
2-methylcyclohexenone | DMSO | E Parameter: -27.50 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
3-methylcyclohexenone | DMSO | E Parameter: -29.60 | Chem. Sci. 2021, 12, 4850-4865 DOI: 10.1039/D0SC06628A | |
tritylium ion (Ph3C+) | 0 | E Parameter: 0.51 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
(4-CF3)2-tritylium ion | E Parameter: 2.28 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(3-Cl)3-tritylium ion | E Parameter: 1.99 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-CF3)-tritylium ion | E Parameter: 1.33 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(3-Cl)-tritylium ion | E Parameter: 1.06 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(3-CF3)-tritylium ion | E Parameter: 1.18 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-Me)-tritylium ion | E Parameter: -0.13 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-Me)2-tritylium ion | E Parameter: -0.70 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-Me)3-tritylium ion | E Parameter: -1.21 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-MeO,3-OMe)-tritylium ion | E Parameter: -1.62 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-OMe,3-Me)-tritylium ion | E Parameter: -1.84 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-MeO)-tritylium ion | E Parameter: -1.59 | Eur. J. Org. Chem. 2011, , 6470-6475 DOI: 10.1002/ejoc.201100910 | ||
(4-MeO,4-Me)-tritylium ion | E Parameter: -2.13 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-MeO)2-tritylium ion | E Parameter: -3.04 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-MeO)3-tritylium ion | E Parameter: -4.35 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-NMe2)-tritylium ion | E Parameter: -7.93 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-NMe2)2-tritylium ion (= Malachite green) | E Parameter: -10.29 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
(4-NMe2)3-tritylium ion (= Crystal violet) | E Parameter: -11.26 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | ||
3-chloro-benzaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | ||
3-fluoro-benzaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | ||
3-methoxy-benzaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | ||
4-fluoro-benzaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | ||
hexanal (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | ||
butanal (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | ||
cinnamaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | ||
p-nitro-cinnamaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 DOI: 10.1021/ja200820m | ||
dibenzo[a,d]tropylium ion | dichloromethane | E Parameter: -0.63 | Liebigs Ann. 1995, , 2005-2009 DOI: 10.1002/jlac.1995199511281 | |
4-phenylbut-3-yn-2-one | 0 | E Parameter: -16.90 | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 DOI: 10.1002/anie.201909803 | |
hex-3-yn-2-one | 0 | E Parameter: -17.90 | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 DOI: 10.1002/anie.201909803 | |
diphenyldiazomethane | 0 | E Parameter: -21.40 | Chem. Eur. J. 2022, 28, e202201376 DOI: 10.1002/chem.202201376 | |
butynone | 0 | E Parameter: -16.60 | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 DOI: 10.1002/anie.201909803 |