Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

C=C(OR)(OSi)

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Enol Ethers
Found 12 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

5-(trimethylsiloxy)-2,3-dihydrofuran
dichloromethaneN  Parameter: 12.56
sN Parameter: 0.70
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

5-(trimethylsiloxy)-2,3-dihydrofuran (in MeCN)
MeCNN  Parameter: 12.34
sN Parameter: 0.72
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

4-methyl-5-(trimethylsiloxy)-2,3-dihydrofuran
dichloromethaneN  Parameter: 11.50
sN Parameter: 0.91
***Eur. J. Org. Chem. 2004, , 2791-2796
DOI: 10.1002/ejoc.200400134
image of molecule

5-(triphenylsiloxy)-2,3-dihydrofuran
dichloromethaneN  Parameter: 11.28
sN Parameter: 0.91
***Eur. J. Org. Chem. 2005, , 1760-1764
DOI: 10.1002/ejoc.200400706
image of molecule

2-(trimethylsiloxy)-5,6-dihydro-4H-pyran
dichloromethaneN  Parameter: 10.61
sN Parameter: 0.86
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

2-(trimethylsiloxy)-5,6-dihydro-4H-pyran (in MeCN)
MeCNN  Parameter: 10.52
sN Parameter: 0.78
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

1-butoxy-1-(t-butyl-dimethylsiloxy)ethene
dichloromethaneN  Parameter: 10.32
sN Parameter: 0.79
****Eur. J. Org. Chem. 2004, , 2791-2796
DOI: 10.1002/ejoc.200400134
image of molecule

1-butoxy-1-(trimethylsiloxy)ethene
dichloromethaneN  Parameter: 10.21
sN Parameter: 0.82
****Eur. J. Org. Chem. 2004, , 2791-2796
DOI: 10.1002/ejoc.200400134
image of molecule

1-methoxy-2-methyl-1-(trimethylsiloxy)propene (in MeCN)
MeCNN  Parameter: 9.11
sN Parameter: 0.88
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

1-methoxy-2-methyl-1-(trimethylsiloxy)propene
dichloromethaneN  Parameter: 9.00
sN Parameter: 0.98
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

1-phenoxy-1-(trimethylsiloxy)ethene
dichloromethaneN  Parameter: 8.23
sN Parameter: 0.81
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

5-(tris(pentafluorophenyl)siloxy)-2,3-dihydrofuran
dichloromethaneN  Parameter: 8.16
sN Parameter: 0.67
***Eur. J. Org. Chem. 2005, , 1760-1764
DOI: 10.1002/ejoc.200400706