Diazo Compounds and Hydrazones

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles

Found 22 Molecules.

Molecule	Solvent	Reactivity Parameters	Reference (sort by title or year)
diazomethane	dichloromethane	N Parameter: 10.48 s_N Parameter: 0.78	Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913
phenyldiazomethane	dichloromethane	N Parameter: 9.35 s_N Parameter: 0.83	Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913
(trimethylsilyl)diazomethane	dichloromethane	N Parameter: 8.97 s_N Parameter: 0.75	Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913
(p-bromophenyl)diazomethane	dichloromethane	N Parameter: 8.87 s_N Parameter: 0.82	J. Am. Chem. Soc. 2018, 140, 16758-16772 DOI: 10.1021/jacs.8b09995
N-methylenepyrrolidin-1-amine (in CH2Cl2)	dichloromethane	N Parameter: 7.84 s_N Parameter: 0.89	Angew. Chem. Int. Ed. 2013, 52, 11900-11904 DOI: 10.1002/anie.201305092
(p-cyanophenyl)diazomethane	dichloromethane	N Parameter: 7.66 s_N Parameter: 0.80	J. Am. Chem. Soc. 2018, 140, 16758-16772 DOI: 10.1021/jacs.8b09995
(p-nitrophenyl)diazomethane	dichloromethane	N Parameter: 7.17 s_N Parameter: 0.83	J. Am. Chem. Soc. 2018, 140, 16758-16772 DOI: 10.1021/jacs.8b09995
1,1-dimethyl-2-methylenehydrazine (in CH2Cl2)	dichloromethane	N Parameter: 6.98 s_N Parameter: 0.85	Angew. Chem. Int. Ed. 2013, 52, 11900-11904 DOI: 10.1002/anie.201305092
2-diazoindan-1-one	dichloromethane	N Parameter: 5.61 s_N Parameter: 0.65	Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005
diphenyldiazomethane	dichloromethane	N Parameter: 5.29 s_N Parameter: 0.92	Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913
ethyl diazoacetate	dichloromethane	N Parameter: 4.91 s_N Parameter: 0.95	Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913
diazocyclopentadiene (in CH2Cl2)	dichloromethane	N Parameter: 4.84 s_N Parameter: 1.06	Synthesis 2023, 55, 354-358 DOI: 10.1055/s-0041-1737327
methyl diazoacetate	dichloromethane	N Parameter: 4.68 s_N Parameter: 0.94	J. Am. Chem. Soc. 2023, 145, 7416-7434 DOI: 10.1021/jacs.2c13872
diazoacetone	dichloromethane	N Parameter: 3.96 s_N Parameter: 0.91	Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913
2-diazo-1-tetralone	dichloromethane	N Parameter: 3.51 s_N Parameter: 0.86	Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005
2-diazocyclohexanone	dichloromethane	N Parameter: 3.44 s_N Parameter: 0.83	Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005
3-diazoindolin-2-one	dichloromethane	N Parameter: 3.16 s_N Parameter: 1.03	Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005
2-diazo-1-benzosuberone	dichloromethane	N Parameter: 2.72 s_N Parameter: 0.96	Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005
2-diazobenzothiophen-3(2H)-one	dichloromethane	N Parameter: 0.40 s_N Parameter: 0.93	Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005
2-diazoindandione	dichloromethane	N Parameter: 0.16 s_N Parameter: 0.86	Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005
diethyl diazomalonate	dichloromethane	N Parameter: -0.35 s_N Parameter: 0.93	Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913
dimethyl diazomalonate	dichloromethane	N Parameter: -1.24 s_N Parameter: 0.81	Angew. Chem. Int. Ed. Engl. 1994, 33, 938-957 DOI: 10.1002/anie.199409381