Carbanions in other solvents
For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions
Found 21 Molecules.
| Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
|---|---|---|---|---|
 cyanide (in MeCN) | MeCN | N Parameter: 16.27 sN Parameter: 0.70 |  | Angew. Chem. Int. Ed. 2005, 44, 142-145 DOI: 10.1002/anie.200461640 |
 chloro(phenylsulfonyl)methanide (in DMF) | DMF | N Parameter: 26.64 sN Parameter: 0.64 |  | Chem. Eur. J. 2008, 14, 6108-6118 DOI: 10.1002/chem.200800329 |
 anion of phenylnitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 12.51 sN Parameter: 0.67 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of p-tolylnitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.58 sN Parameter: 0.64 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of nitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 14.02 sN Parameter: 0.61 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of nitroethane (in DMF) | DMF | N Parameter: 22.21 sN Parameter: 0.48 | | Chem. Eur. J. 2008, 14, 6108-6118 DOI: 10.1002/chem.200800329 |
 anion of nitroethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.41 sN Parameter: 0.67 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of malononitrile (in 91M9AN) | MeOH-MeCN mix | N Parameter: 18.21 sN Parameter: 0.69 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of ethyl cyanoacetate (in 91M9AN) | MeOH-MeCN mix | N Parameter: 18.59 sN Parameter: 0.65 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of dimethyl malonate (in 91M9AN) | MeOH-MeCN mix | N Parameter: 18.24 sN Parameter: 0.64 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of 4-nitrobenzyl-CN (in MeCN) | MeCN | N Parameter: 20.10 sN Parameter: 0.71 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 |
 anion of 4-nitrobenzyl trifluoromethyl sulfone (in 91M9AN) | MeOH-MeCN mix | N Parameter: 18.24 sN Parameter: 0.66 | | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b |
 anion of 4-cyanobenzyl trifluoromethyl sulfone (in MeCN) | MeCN | N Parameter: 15.62 sN Parameter: 0.99 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 |
 anion of 4-cyanobenzyl trifluoromethyl sulfone (in 91M9AN) | MeOH-MeCN mix | N Parameter: 19.49 sN Parameter: 0.63 | | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b |
 anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in MeCN) | MeCN | N Parameter: 16.15 sN Parameter: 0.99 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 |
 anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN) | MeOH-MeCN mix | N Parameter: 20.72 sN Parameter: 0.58 | | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b |
 anion of 2-nitropropane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 12.20 sN Parameter: 0.71 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of (4-NO2-C6H4)CH2SO2Ph (in MeCN) | MeCN | N Parameter: 19.90 sN Parameter: 0.66 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 |
 anion of (4-nitrophenyl)nitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 14.05 sN Parameter: 0.72 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of (4-cyanophenyl)nitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.92 sN Parameter: 0.74 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |
 anion of (3-nitrophenyl)nitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 14.75 sN Parameter: 0.71 | | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 |