H-B hydride donors
For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles
Found 23 Molecules.
Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
---|---|---|---|---|
borane-2,6-lutidine-complex | dichloromethane | N Parameter: 10.33 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-4-methoxypyridine-complex | dichloromethane | N Parameter: 11.01 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-4-tBu-pyridine-complex | dichloromethane | N Parameter: 10.46 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-DMAP-complex | dichloromethane | N Parameter: 12.44 sN Parameter: 0.76 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-N,N-diethylaniline-complex | dichloromethane | N Parameter: 8.53 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-N,N-diisopropylaniline-complex | dichloromethane | N Parameter: 8.84 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-N-ethyl-N-isopropylaniline-complex | dichloromethane | N Parameter: 9.12 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-pyridine-complex | dichloromethane | N Parameter: 10.01 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-triethylamine-complex | dichloromethane | N Parameter: 8.90 sN Parameter: 0.75 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
borane-trimethylamine-complex | dichloromethane | N Parameter: 7.97 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
bromoborane-triethylamine-complex | dichloromethane | N Parameter: 7.49 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
Bu4NBH4 (in DMSO) | DMSO | N Parameter: 14.94 sN Parameter: 0.79 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
cyanoborate ion (in water) | water | N Parameter: 9.99 sN Parameter: 0.54 | Org. Biomol. Chem. 2023, 21, 85-88 DOI: 10.1039/D2OB02041F | |
dipp Imd boronate | dichloromethane | N Parameter: 9.55 sN Parameter: 0.81 | Org. Lett. 2012, 14, 82-85 DOI: 10.1021/ol202836p | |
KBH4 (in DMSO) | DMSO | N Parameter: 15.14 sN Parameter: 0.77 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
Me2 Imd boronate | dichloromethane | N Parameter: 11.88 sN Parameter: 0.71 | Org. Lett. 2012, 14, 82-85 DOI: 10.1021/ol202836p | |
NaB(OAc)3H (in DMSO) | DMSO | N Parameter: 14.45 sN Parameter: 0.76 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
NaBH3(CN) (in DMSO) | DMSO | N Parameter: 11.52 sN Parameter: 0.67 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
NaBH4 (in DMSO) | DMSO | N Parameter: 14.74 sN Parameter: 0.81 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
tetrahydroborate ion (in water) | water | N Parameter: 12.10 sN Parameter: 0.79 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
[H-B(2,4,6-F3C6H2)3]- [NEt4]+ | MeCN | N Parameter: 14.13 sN Parameter: 0.61 | Angew. Chem. Int. Ed. 2015, 54, 14508-14512 DOI: 10.1002/anie.201507298 | |
[H-B(2,6-F2C6H3)3]- [NEt4]+ | MeCN | N Parameter: 13.97 sN Parameter: 0.66 | Angew. Chem. Int. Ed. 2015, 54, 14508-14512 DOI: 10.1002/anie.201507298 | |
[H-B(C6F5)3]- [NEt4]+ | MeCN | N Parameter: 10.04 sN Parameter: 0.73 | Angew. Chem. Int. Ed. 2015, 54, 14508-14512 DOI: 10.1002/anie.201507298 |