Allyl Element Compounds
For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
Found 38 Molecules.
Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
---|---|---|---|---|
allyltrimethylsilane | dichloromethane | N Parameter: 1.68 sN Parameter: 1.00 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
allyltriphenylstannane | dichloromethane | N Parameter: 3.09 sN Parameter: 0.90 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(2-methylallyl)trimethylsilane | dichloromethane | N Parameter: 4.41 sN Parameter: 0.96 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
allyltributylstannane | dichloromethane | N Parameter: 5.46 sN Parameter: 0.89 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(2-methylallyl)tributylstannane | dichloromethane | N Parameter: 7.48 sN Parameter: 0.89 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
allyltriphenylsilane | dichloromethane | N Parameter: -0.13 sN Parameter: 1.21 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(2-methylallyl)triphenylsilane | dichloromethane | N Parameter: 4.17 sN Parameter: 0.79 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
allylchlorodimethylsilane | dichloromethane | N Parameter: -0.57 sN Parameter: 1.06 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
trimethyl(prenyl)silane | dichloromethane | N Parameter: 0.90 sN Parameter: 1.17 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(2-methylallyl)triphenylgermane | dichloromethane | N Parameter: 4.67 sN Parameter: 0.81 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
allyl-tert.butyl-dimethylsilane | dichloromethane | N Parameter: 1.80 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltriethylsilane | dichloromethane | N Parameter: 1.93 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltriisopropylsilane | dichloromethane | N Parameter: 2.04 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltri-n-butylsilane | dichloromethane | N Parameter: 2.09 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltrihexylsilane | dichloromethane | N Parameter: 2.11 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(Z)-but-2-enyltrimethylsilane | dichloromethane | N Parameter: 1.69 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(E)-but-2-enyltrimethylsilane | dichloromethane | N Parameter: 1.94 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2,3-dimethylbut-2-enyl)triethylsilane | dichloromethane | N Parameter: 3.15 sN Parameter: 1.15 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
3-(trimethylsilyl)cyclopentene | dichloromethane | N Parameter: 1.77 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
3-(trihexylsilyl)cyclopentene | dichloromethane | N Parameter: 1.98 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2-methylallyl)trichlorosilane | dichloromethane | N Parameter: -0.57 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltriphenylgermane | dichloromethane | N Parameter: 1.20 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
prenyl-tributylstannane | dichloromethane | N Parameter: 4.74 sN Parameter: 1.15 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2-methylallyl)triphenylstannane | dichloromethane | N Parameter: 5.13 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(allyl)dicarbonyl(cyclopentadienyl)iron(II) | dichloromethane | N Parameter: 6.78 sN Parameter: 0.95 | Helv. Chim. Acta 2005, 88, 1754-1768 DOI: 10.1002/hlca.200590137 | |
(2-methylallyl)dicarbonyl(cyclopentadienyl)iron(II) | dichloromethane | N Parameter: 8.45 sN Parameter: 0.83 | Helv. Chim. Acta 2005, 88, 1754-1768 DOI: 10.1002/hlca.200590137 | |
allyltris(trimethylsilyl)silane | dichloromethane | N Parameter: 1.95 sN Parameter: 0.98 | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e | |
(2-methylallyl)tris(trimethylsilyl)silane | dichloromethane | N Parameter: 4.63 sN Parameter: 0.87 | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e | |
2-phenyl-allyltrimethylsilane | dichloromethane | N Parameter: 5.38 sN Parameter: 0.89 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
(1H-inden-1-yl)trimethylstannane (in CH2Cl2) | dichloromethane | N Parameter: 6.68 sN Parameter: 0.81 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
(1H-inden-1-yl)trimethylsilane (in CH2Cl2) | dichloromethane | N Parameter: -0.10 sN Parameter: 1.05 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2) | dichloromethane | N Parameter: -0.64 sN Parameter: 1.10 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
(1H-inden-1-yl)zinc(II) chloride*LiCl (in DMSO) | DMSO | N Parameter: 18.10 sN Parameter: 0.46 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
(1H-inden-1-yl)zinc(II) bromide*LiBr (in DMSO) | DMSO | N Parameter: 15.60 sN Parameter: 0.51 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
potassium allyltrifluoroborate (in MeCN) | MeCN | N Parameter: 5.29 sN Parameter: 0.87 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 8.71 sN Parameter: 0.80 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
lithium 2-allyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 11.20 sN Parameter: 0.64 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
lithium (E)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(but-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 9.49 sN Parameter: 0.82 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 |